“…Such a technique could minimize CO 2 emissions and be used in the chemical process industries and fuels. Photocatalytic CO 2 reduction is an excellent green chemistry technology for directly converting CO 2 by natural sunlight into fuels such as CO, CH 4 , CH 3 OH, etc. , It is known that the CO 2 photocatalysis efficiency of photocatalyst depends on its physicochemical properties, the position of the conduction band (CB), the ability for light absorption, photon energy, light intensity, surface catalytic active sites, e – /h + separation, and adsorption and desorption of reactants and intermediates. − However, semiconductors are promising photocatalysts, − in specific TiO 2 nanoparticles, due to their stability, abundance, cost-effectiveness, and corrosion resistance. The only barrier for TiO 2 is its wide bandgap which can be enhanced by doping with other nonmetals, metals, or their oxides. − …”