“…It is well known that adsorption of nonionic surfactant on a solid particle surface stems from the van der Waals force that exists between the solid surface and the surfactant, based on hydrophobicity[26]. Using this principle and the above findings, we hypothesize that the relatively positive surface charge of CCNPs at pH 7 could lead to retarded APG adsorption on the surface, and a difference in adsorption structure compared with the observations made at pH 10.As previously described, CCNPs were identified to have prominent adsorption bands at 713, 875, 1464, and 1796 cm -1 , which are common characteristics of CO3 2-[27]. Bands were also observed at 2512 and 3442 cm -1 , and identified as the HCO 3 -absorption bands originating from partial dissolution of CaCO 3 in water[28], and -OH of water molecules, respectively.…”