2018
DOI: 10.1016/j.electacta.2018.03.030
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Immobilization of functionalized iron(II) clathrochelates with terminal (poly)aromatic group(s) on carbonaceous materials and their detailed cyclic voltammetry study

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Cited by 12 publications
(11 citation statements)
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“…There is hence a simple correlation between the number of polyaromatic groups per a clathrochelate molecule (from one to six) and the strength of adsorption. A similar trend was reported earlier [7] while using RGO used as carbonaceous substrate.…”
Section: Study Of the Physisorption Of Iron(ii) Clathrochelatessupporting
confidence: 89%
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“…There is hence a simple correlation between the number of polyaromatic groups per a clathrochelate molecule (from one to six) and the strength of adsorption. A similar trend was reported earlier [7] while using RGO used as carbonaceous substrate.…”
Section: Study Of the Physisorption Of Iron(ii) Clathrochelatessupporting
confidence: 89%
“…Three different complexes of interest, namely FeBd 2 ((Phen(CH 2 ) 3 S)GmH)(BF) 2 , FeBd 2 ((Phen(CH 2 ) 3 S) 2 Gm)(BF) 2 (where Bd 2stands for α-benzildioxime dianion and Gm stands for glyoxime residue) and Fe((Phen(CH 2 ) 3 S) 2 Gm) 3 (Bn-C 4 H 9 ) 2 , were prepared as described elsewhere. [6,7] Carbon paper (CP) Sigracet GDL 39 BC (SGL Group) was used in adsorption experiments.…”
Section: Methodsmentioning
confidence: 99%
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“…An original method of using graphene as a support of molecular electrocatalysts for hydrogen evolution was demonstrated in the studies of Russian researchers, including those performed at the National Research Center Kurchatov Institute [ 126 ]. The clathrochelate complexes of Fe, Co, and Ru can be adsorbed on the developed RGO surface, which makes it possible to significantly increase the efficiency and productivity of the cathode of a PEM water electrolyzer [ 127 , 128 ]. A similar approach can be used in the case of molecular electrocatalysts of the ORR, etc.…”
Section: Application Of Graphene In Electrocatalytic Layers Of Polmentioning
confidence: 99%
“…Most often, an SCO is encountered in (pseudo)­octahedral complexes of iron­(II) in a N6-coordination environment, , such as provided by many bi- and tridentate N-donor heterocyclic ligands or ligands of higher denticity. From the latter group, a unique class of extended-tripodal (cage) ligands produces rigid and chemically stable transition-metal complexes, so-called clathrochelates, which can be easily synthesized by self-assembly on an appropriate metal ion, functionalized at several (apical and ribbed) positions by various functional groups , and applied onto surfaces via chemical bonding or deposition from solutions, all being important qualities for practical applications in molecular sensing, electronics, and spintronics . The HS cobalt­(II) clathrochelates (or pseudoclathrochelates if one capping boron atom is missing; Scheme ) often show a single-molecule magnet (SMM) behavior with some record values for cobalt­(II) compounds, , and in rare cases, , they undergo a temperature-induced SCO, sometimes anticooperative, stemming from a trigonal-prismatic geometry imposed by the rigid cage ligand and its resistance to distortions .…”
Section: Introductionmentioning
confidence: 99%