<i>In situ</i> quantization of ferroferric oxide embedded in 3D microcarbon for ultrahigh performance sodium-ion batteries

Li, Qi; Zhang, Yi-Wei; Zuo, Zicheng; Ye, Xin; Yang, Chengkai; Wu, Bin; Zhang, Xin‐Xiang; Zhou, Henghui

doi:10.1039/c6ta01836j

Cited by 47 publications

(32 citation statements)

References 61 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Efforts towards improving the capacity and cycling stability of iron-oxide based electrodes have been made by many groups. 34,[133][134][135][136][137]164 3D porous γ-Fe2O3 nanoparticles with particles 5 nm in size uniformly embedded in a porous carbon matrix were fabricated as shown in Fig. 11.…”

Section: Metal Oxidesmentioning

confidence: 99%

Recent progress on sodium ion batteries: potential high-performance anodes

Zheng

Zhang

et al. 2018

Energy Environ. Sci.

616

343

View full text Add to dashboard Cite

show abstract

Section: Metal Oxidesmentioning

confidence: 99%

Recent progress on sodium ion batteries: potential high-performance anodes

Zheng

Zhang

et al. 2018

Energy Environ. Sci.

616

343

View full text Add to dashboard Cite

show abstract

“…Ball in ball hierarchical NiO/Ni coated with graphene layer has also been employed for the sodium ion battery. [178a] An ultrafast rechargeable sodium ion battery has been demonstrated with hierarchically 3D carbon‐coated Fe 3 O 4 quantum dots derived from Fe‐MOF . Homogeneously distributed Co 3 ZnC polyhedrons in in situ generated nitrogen doped carbon nanotubes from bimetallic ZIF have been synthesized and employed as the anode material for the Na ion battery .…”

Section: Energy Storagementioning

confidence: 99%

Metal Organic Framework Derived Materials: Progress and Prospects for the Energy Conversion and Storage

2018

View full text Add to dashboard Cite

Exploring new materials with high efficiency and durability is the major requirement in the field of sustainable energy conversion and storage systems. Numerous techniques have been developed in last three decades to enhance the efficiency of the catalyst systems, control over the composition, structure, surface area, pore size, and moreover morphology of the particles. In this respect, metal organic framework (MOF) derived catalysts are emerged as the finest materials with tunable properties and activities for the energy conversion and storage. Recently, several nano- or microstructures of metal oxides, chalcogenides, phosphides, nitrides, carbides, alloys, carbon materials, or their hybrids are explored for the electrochemical energy conversion like oxygen evolution, hydrogen evolution, oxygen reduction, or battery materials. Interest on the efficient energy storage system is also growing looking at the practical applications. Though, several reviews are available on the synthesis and application of MOF and MOF derived materials, their applications for the electrochemical energy conversion and storage is totally a new field of research and developed recently. This review focuses on the systematic design of the materials from MOF and control over their inherent properties to enhance the electrochemical performances.

show abstract

“…In the recent decades, MOFs have been focused on due to their large porosity, huge specific area, and structural diversity . Nonetheless, a poor electrical conductive capacity and stability, serious shortcomings of MOFs, have been a large barrier for MOFs to acquire better performance in batteries . Recent years, it has been proven that graphene‐based materials have the ability to overcome these weaknesses.…”

Section: Batteriesmentioning

confidence: 99%

Metal‐Organic Frameworks/Graphene‐Based Materials: Preparations and Applications

Zheng

Xue

et al. 2018

Adv Funct Materials

246

107

View full text Add to dashboard Cite

Metal-organic frameworks (MOFs), a new class of crystalline porous materials, can be applied in many fields as adsorbents, supercapacitors, catalysts, and so on because of, among others, their superior properties of large surface area, tunable pore size, diverse structures. However, the low stability and selectivity of traditional MOFs indicate that they are not the best configuration for the applications outlined above. In this case, a type of composite made from an assembly of graphene-based materials and MOFs that exhibits the advantages of the parent materials has attracted widespread attention in recent years. This review provides an overview of the recent developments of MOF/graphene-based materials, focusing on their applications in gas separation/storage, water purification, chemical sensors, batteries, supercapacitors, and catalysts, as well as their preparation methods.The ORCID identification number(s) for the author(s) of this article can be found under https://doi.org/10.1002/adfm.201804950. traditional method, they can be excellent alternatives of single MOFs to overcome the above-mentioned difficulties. [34][35][36][37][38] Graphene-based materials have recently introduced new possible applications because of their unique structure and low toxicity, as well as their excellent electronic, thermal, electrochemical, and mechanical properties. [39] More recently, many reports have confirmed that the introduction of graphene-based materials into other materials can lead to surprising improvements in electronic conductivity and stability. [38,40] Under these circumstances, it is reasonable to consider whether composites made from the assembly of graphene-based materials and MOFs possess extraordinary characteristics given that the parent materials have complementary properties. [40][41][42] Naturally, the idea of hybridizing graphene derivatives with MOFs materialized and soon attracted widespread attention. [43][44][45] According to recent research, composites of MOF/graphene-based materials can integrate the advantages and mitigate the shortcomings of the individual components perfectly, enabling the composites to possess improved stability, enhanced electrical conductivity, high selectivity, and template effects. [34,[46][47][48][49] With the combination of MOF and graphene-based materials, the unexpected interactions take place and bring unique performance in many applications. Thanks to the ionic groups and the aromatic sp 2 domains, graphene-based materials can not only function as structural nodes, but also participate in bonding interactions, which would be more active in MOFs. What's more, carboxylate and pyridine groups of graphene-based materials play important part in the assemble, which could enhance the coordination bonding and guide the growth of MOF, providing a more beneficial structure. These special interactions are unique in MOF/graphenebased materials, which indicates that this kind of materials deserve more attention. As concluded in Scheme 1, the addition of graphene-based material...

show abstract

In situ quantization of ferroferric oxide embedded in 3D microcarbon for ultrahigh performance sodium-ion batteries

Abstract: Through in situ quantization, Fe3O4 was uniformly dispersed in 3D microcarbon matrices of ultrafast and stable sodium ion batteries.

Cited by 47 publications

References 61 publications

Recent progress on sodium ion batteries: potential high-performance anodes

Recent progress on sodium ion batteries: potential high-performance anodes

Metal Organic Framework Derived Materials: Progress and Prospects for the Energy Conversion and Storage

Metal‐Organic Frameworks/Graphene‐Based Materials: Preparations and Applications

Contact Info

Product

Resources

About