“…Usual surfactant molecules are here discarded, as they are tethered at one end‐molecule only, making it possible for the sheets to delaminate and, as the size needed for the alkyl chain will be probably too long (over 5–6 nm length), thus rendering the surfactant too waxy to mix intimately with LDH platelets. As far as the size of the basal spacing is concerned, polymeric bola‐amphiphiles, [ 22a,b,c ] in particular α,ω‐carboxylate‐terminated hydrophobic backbones (Figure S1, Supporting Information) are reported to generate an interlayer space as large as 5–6 nm, [ 23a,b ] close here to the size of the QDs. It is found that LDH phases are highly compatible with such biterminal molecules, which is reminiscent of terephthalate intercalation pioneered by Drezdon.…”