cis,trans,cis,cis-7-tert-Butyldimethylsilyloxy-4,10-dimethyltetracyclo[5.4.1.04,12.010,12]dodecan-2-one

Weyermann, Philipp; Keese, Reinhart; Stœckli-Evans, Helen

doi:10.1107/s1600536810000887

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Cited by 3 publications

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“…9 An X-ray analysis of 3 provided detailed information about its structure. 10 The bond angles C1eC12eC7 and C4e12eC10 are 128.9 and 122.8 , respectively. The bond length C10eC14 of 1.616 A is significantly longer than that of C4eC12 (1.524 A).…”

Section: Resultsmentioning

confidence: 99%

Synthesis and reactions of two stereoisomeric [4.5.5.5]fenestranes with bridgehead substituents

Weyermann

Keese

2011

Tetrahedron

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Section: Resultsmentioning

confidence: 99%

Synthesis and reactions of two stereoisomeric [4.5.5.5]fenestranes with bridgehead substituents

Weyermann

Keese

2011

Tetrahedron

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Fenestrane in der Synthese: einzigartige und inspirierende Grundgerüste

et al. 2013

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Das Gerüst von Fenestranen ist einzigartig, da es vier kondensierte Ringe und ein verzerrtes vierfach koordiniertes zentrales Kohlenstoffatom aufweist, dessen Bindungswinkel größer als die regulären 109°28′′ sind. In diesem Kurzaufsatz wird eine detaillierte Übersicht über die Entwicklungen bezüglich dieser Verbindungsklasse, einschließlich ihrer Synthese, für den Zeitraum seit 2006 gegeben. In den vergangenen Jahren wurden Naturstoffe, die als Heterofenestrane klassifiziert werden können, isoliert, und deren Synthesen werden ebenfalls diskutiert.

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Fenestranes in Synthesis: Unique and Highly Inspiring Scaffolds

et al. 2013

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The scaffold of fenestranes is quite unique, as it contains four condensed cycles and a distorted tetracoordinated central carbon atom with bond angles greater than the regular 109°28". In this Minireview, a detailed overview on the developments regarding this compound class, including their synthesis, is given for the time period since 2006. In the past years, natural products that belong to the class of heterofenestranes have been isolated and their syntheses will also be discussed.

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cis,trans,cis,cis-7-tert-Butyldimethylsilyloxy-4,10-dimethyltetracyclo[5.4.1.0^4,12.0^10,12]dodecan-2-one

Cited by 3 publications

References 7 publications

Synthesis and reactions of two stereoisomeric [4.5.5.5]fenestranes with bridgehead substituents

Synthesis and reactions of two stereoisomeric [4.5.5.5]fenestranes with bridgehead substituents

Fenestrane in der Synthese: einzigartige und inspirierende Grundgerüste

Fenestranes in Synthesis: Unique and Highly Inspiring Scaffolds

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