Hypergolic propellants based on hydrogen peroxide and organic compounds: historical aspect and current state

Guseinov, Sh. L.; Fedorov, S. G.; Kosykh, V. A.; Стороженко, П. А.

doi:10.1007/s11172-018-2314-1

Cited by 26 publications

(9 citation statements)

References 26 publications

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“…The historical role of hydrogen peroxide has been as a mono-propellant and a liquid oxidizer. Guseinov et al, have reviewed hypergolic propellants based on hydrogen peroxide and organic compounds in terms of historical aspect and current state in 2018 [5].…”

Section: Hypergolic Systems With Hydrogen Peroxide Oxidizermentioning

confidence: 99%

Hypergolic Systems based on Hydrogen Peroxide Oxidizer

Türker

2023

EJCS

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Hydrogen peroxide, H2O2, is a promising and nontoxic oxidant. In recent years considerable attention has been paid to the development of hypergolic system compositions, because the use of them not only markedly simplifies the engine design and rocket system operation but also provides the possibility of their repeated use. Moreover, their high performance, high environmental compatibility and low toxicity make them highly preferable. The present review considers recent works on hypergolic systems involving hydrogen peroxide as the oxidizer and various green propellants of organic and inorganic nature with or without certain additives.

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Section: Hypergolic Systems With Hydrogen Peroxide Oxidizermentioning

confidence: 99%

Hypergolic Systems based on Hydrogen Peroxide Oxidizer

Türker

2023

EJCS

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“…Hydrogen peroxide is still in use today as a monopropellant in the reaction control system of the Soyuz descent module [4]. The first hypergolic fuels with hydrogen peroxide were developed during the Second World War in Germany [5].…”

Section: Alternative Green Bipropellantsmentioning

confidence: 99%

Green bipropellant development – A study on the hypergolicity of imidazole thiocyanate ionic liquids with hydrogen peroxide in an automated drop test setup

Lauck

Balkenhohl

Negri

et al. 2021

Combustion and Flame

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“…Most of the reported hypergolic ionic liquids exhibited hypergolic ignition when in contact with toxic but highly reactive WFNA, RFNA, and N 2 O 4 oxidizers. High test peroxide (>90%H 2 O 2 , HTP) is a relatively green oxidizer with less toxicity and low vapor pressure, which could be stored under ambient conditions. , The first hypergolic fuels with HTP were developed in the 1930s, and HTP has been reliably utilized as a monopropellant in the reaction control system of the Soyuz descent module today. However, due to relatively low oxidation potential in comparison with WFNA, RFNA, and N 2 O 4 , very few pure ionic liquid substances could be hypergolic successfully with HTP. − …”

Section: Introductionmentioning

confidence: 99%

Designing Difunctional Promoters for Hypergolic Ignitions of Green Bipropellants Combining Ionic Liquids with H₂O₂

Wang

Jin

et al. 2022

Ind. Eng. Chem. Res.

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The emergence of tetrahydroborate (BH 4 − )/ cyanoborohydride (BH 3 CN − ) anion-based ionic liquid fuels in combination with high test peroxide (>90%H 2 O 2 , HTP) oxidizers has accelerated the greening of bipropellants. However, most BH 4 − and BH 3 CN − anion-based ionic liquids are sensitive to water, making it difficult to store them. Here, novel difunctional promoters are designed for hypergolic ignition of BH 4 − / BH 3 CN − anion-free ionic liquids with 90%H 2 O 2 . The transition metal in anions of promoters is expected to catalyze the exothermic decomposition of H 2 O 2 , and the substituted borohydride in cations of promoters acts as the ignition source. These novel difunctional promoters show good solubility in commercially available 1-allyl-3-methylimidazolium dicyanamide and 1-butyl-3methylimidazolium dicyanamide ionic liquid fuels, and the composite fuels exhibit high density, acceptable viscosity, and high thermostability. The addition of difunctional promoters ensures the smooth hypergolic ignition of BH 4 − /BH 3 CN − anion-free ionic liquid fuels with a minimum ignition delay time of 34.0 ms, and no apparent microexplosion and secondary combustion are observed during the ignition process. With the increase in the amount of the promoter, density specific impulses of the composite fuels improve gradually. This work provides a platform strategy for designing promoters by synergy of cations and anions and makes efforts to seek green bipropellants.

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Hypergolic propellants based on hydrogen peroxide and organic compounds: historical aspect and current state

Cited by 26 publications

References 26 publications

Hypergolic Systems based on Hydrogen Peroxide Oxidizer

Hypergolic Systems based on Hydrogen Peroxide Oxidizer

Green bipropellant development – A study on the hypergolicity of imidazole thiocyanate ionic liquids with hydrogen peroxide in an automated drop test setup

Designing Difunctional Promoters for Hypergolic Ignitions of Green Bipropellants Combining Ionic Liquids with H₂O₂

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Hypergolic propellants based on hydrogen peroxide and organic compounds: historical aspect and current state

Cited by 26 publications

References 26 publications

Hypergolic Systems based on Hydrogen Peroxide Oxidizer

Hypergolic Systems based on Hydrogen Peroxide Oxidizer

Green bipropellant development – A study on the hypergolicity of imidazole thiocyanate ionic liquids with hydrogen peroxide in an automated drop test setup

Designing Difunctional Promoters for Hypergolic Ignitions of Green Bipropellants Combining Ionic Liquids with H2O2

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Designing Difunctional Promoters for Hypergolic Ignitions of Green Bipropellants Combining Ionic Liquids with H₂O₂