Based on the experimental hyperfine structure data given in our previous study, the multi-configuration method has been used to calculate the fine structure of the odd parity configurations 3d4s4p, 4s 2 4p and 3d 2 4p of neutral Scandium taking into account configuration interaction effects. Magnetic dipole hyperfine structure constants are analysed in the effective-operator formalism for the isotope 45 Sc. Relativistic one-electron parameters of the magnetic dipole hyperfine structure a k s k l nl (k s k l = 01, 10, 12) were fitted to the experimental data by a least-squares fit procedure. Theoretical predictions for the magnetic dipole hyperfine structure constants A for all levels of the three configurations are given.