Hydrothermal synthesis and single-crystal structural characterization of the layered vanadium(IV) phosphate VOC6H5PO3.cntdot.H2O

Huan, G.; Jacobson, Allan J.; Johnson, Jack W.; Corcoran, Edward W.

doi:10.1021/cm00008a002

Cited by 77 publications

(43 citation statements)

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“…Earlier work in this area was by Jacobson and co-workers, [104] Zubieta and co-workers, [105] and FØrey and co-workers. Earlier work in this area was by Jacobson and co-workers, [104] Zubieta and co-workers, [105] and FØrey and co-workers.…”

Section: Phosphonatesmentioning

confidence: 99%

“…Diphosphonate groups are more versatile for the formation of higher dimensional structures through pillaring of the layers and other similar structural arrangements. Earlier work in this area was by Jacobson and co-workers, [104] Zubieta and co-workers, [105] and FØrey and co-workers. [106] The use of the methylene diphosphonate anion in preparing vanadium compounds has given rise to zero-, [105b] one-, [105b] and twodimensional structures.…”

Section: Phosphonatesmentioning

confidence: 99%

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Open‐Framework Structures of Transition‐Metal Compounds

2008

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Inorganic framework solids are no longer limited to just the silicates and phosphates. Recent research has revealed that carboxylates, arsenates, sulfates, selenates, selenites, germanates, phosphites can also form such structures. One of the emerging areas combines the rich coordination chemistry of the central metal ions of many of these structures with the flexibility and functionality of the organic linkers to give rise to organic-inorganic hybrid compounds. The compounds of the transition-metals appear to provide many variations arising from their coordination preferences, ligand geometry, and the valence state. In addition, the combination of the magnetic nature of the transition metal center with the channel structure of open frameworks suggests interesting potential applications. In this Review the synthesis, structures and properties of the various transition-metal open-framework compounds are discussed.

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Section: Phosphonatesmentioning

confidence: 99%

Section: Phosphonatesmentioning

confidence: 99%

Open‐Framework Structures of Transition‐Metal Compounds

2008

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“…Such features are crucial in the design of effective catalysts or sorptive materials. It is noteworthy, in this regard, that the prototypical layered oxovanadium organophosphonate [VO(O PPh)(H O)] 3 (8,9) selectively intercalates alcohols by coordination of the substrate to the vanadium atom of the inorganic layers.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Structure of Cs[(VO)2(OH)(O3PCH2CH2PO3)]: A Two-Dimensional Solid with Pillared Layers

Bonavia

Haushalter²,

et al. 1997

Journal of Solid State Chemistry

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“…8 The vanadyl organophosphonate system has proved particularly fruitful and is represented by molecular clusters of various nuclearities, and one-, two-and three-dimensional phases. [9][10][11] In common with metal organophosphonates in general, lamellar structures predominate for the vanadyl organophosphonate subclass, with [(VO)-(H 2 O)(PhPO 3 )] 12 providing the structural prototype. Lamellar vanadyl organophosphonates possess structurally well defined internal void spaces and coordination sites which allow intercalation of substrate molecules.…”

mentioning

confidence: 99%