The effect of the addition of Gadolinium oxide (Gd2O3) up to 10 wt.% in
bauxite was studied and its thermal behavior compared with pure bauxite. The
incorporation of Gd2O3 is of technological interest for the design of smart
traceable ceramic proppants used for unconventional gas and oil well
stimulation. These high macroscopic neutron capture cross section proppants
are used to obtain relevant information, such as the location and height of
the created hydraulic fractures, through a neutron based detection
technology. The study comprised a set of thermal and sintering behavior
analyses up to 1500 ?C of mixtures up to 10 wt.% addition of Gd2O3. The
developed texture and microstructure was also assessed. A simple mechanical
characterization was performed as well. Fully-dense pore-free
microstructures were developed, with alumina and mullite as the main
crystalline phases. Gadolinium secondary and ternary alumino-silicate phases
were also observed after thermal treatment. These present a needle
morphology that might result in reinforcement mechanisms. No important
glassy phase was detected; although sintering was enhanced, the Gd2O3 oxide
main role was found to be as a sintering aid rather than a strict flux
agent. The mechanical behavior remained fragile with the rare oxide
addition. In fact, the mechanical resistance increased up to 20 wt.% for the
10 wt.% added sample. The oxide addition together with the bauxite
dehydroxilation mass loss resulted in materials with up to 1.5 x 105 (c.u.)
macroscopic neutron capture cross section materials. The obtained results
permit to define design strategies of high macroscopic neutron capture
ceramic materials for wellbore and developed fractures description.