Hybrid polymerization of iso-butyl vinyl ether

Jiang, Bo; Yang, Li‐Xing; Zhou, Yong; Huang, Guanglin; Lin, Liangcai

doi:10.1016/s0969-806x(01)00665-x

Cited by 2 publications

(2 citation statements)

References 24 publications

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“…A possible way to produce a hybrid structure is co-polymerization of different functional monomers, which many researchers have focused on from the 1980s [5][6][7]. Another way is polymerization of a monomer bearing two types of active group in one molecule.…”

Section: Introductionmentioning

confidence: 99%

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Novel Bisphenol A Epoxide–Acrylate Hybrid Oligomer and Its Photopolymerization

Xiao

Nie

2008

Designed Monomers and Polymers

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An epoxide-acrylate hybrid oligomer was synthesized by reaction of bisphenol A epoxy resin and acrylic acid and its photopolymerization kinetics were investigated using real-time infrared spectroscopy. The influences of photoinitiator concentration on the polymerization kinetics and the unique photopolymerization kinetic character were compared with the blend system of epoxy resin and epoxy acrylate and discussed. The hybrid oligomer showed some inter-group interaction in the photopolymerization process, which could decrease the oxygen inhibition to radical process. The mechanical properties were explored by DMA. Hybrid oligomer cured film showed a more uniform polymer net and higher T g than the blend of epoxy acrylate and epoxy resin.

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Section: Introductionmentioning

confidence: 99%

“…Some papers focus on design and synthesis of hybrid monomers [5,[8][9][10], but most of them only deal with small molecule compounds, which are difficult to be used as oligomer in photocurable coatings. The photopolymerization kinetics of hybrid monomer have hardly been discussed to date.…”

Section: Introductionmentioning

confidence: 99%

Novel Bisphenol A Epoxide–Acrylate Hybrid Oligomer and Its Photopolymerization

Xiao

Nie

2008

Designed Monomers and Polymers

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Radiation curing of collagen/divinyl ether enhanced by pyridinium salts

Jiang

Zhou

Zheng

et al. 2005

J of Applied Polymer Sci

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ABSTRACT:The radiation curings of collagen/divinyl ether enhanced by several nitrogenous onium salts having relatively stable nonnucleophilic anion (PF 6 Ϫ ) have been investigated. Results of glass transformation temperature (T g ) measurements and IR spectroscopy analysis and solvent extractions to the crosslinked polymer networks demonstrate that the curing reactions have been initiated by electron beam irradiation in the mixture system of collagen/ divinyl ether and onium salts under different atmosphere conditions. The experimental data show the presence of an approximating linear relationship between double bond conversion and gel fraction after the calculation of conversion from IR spectra in oligomer and the measure of gel content at different total radiation doses. Practical values approximate theoretical values in applying gelation theory of the relationship of gel fraction and double bond conversion. In comparison with the influence of different inhibitors, the curing reaction with pyridinium salts is a polymerization and crosslinking of cationic mechanism, but radicals play an important role in initiation.

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Hybrid polymerization of iso-butyl vinyl ether

Cited by 2 publications

References 24 publications

Novel Bisphenol A Epoxide–Acrylate Hybrid Oligomer and Its Photopolymerization

Novel Bisphenol A Epoxide–Acrylate Hybrid Oligomer and Its Photopolymerization

Radiation curing of collagen/divinyl ether enhanced by pyridinium salts

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