It is difficult to assess fatalities due to high temperature corrosion, such as plant closure time, production loss, decrease in productivity, contamination, etc. In this context, the AISI 422 martensitic steel is a popular choice for high temperature applications due to its unique properties. The durability of this material can be increased by coating technology. The Ni-20Cr composite powder is a highly recommended choice for high-temperature applications. In this research, Ni-20Cr coating was sprayed on AISI 422 steel, using a flame spray process with two different thicknesses of 250–350 µm and 350–450 µm. Corrosion studies have been carried out at temperatures of 600 °C and 900 °C for Na2SO4 + 60%V2O5 salt solution environment. The corrosion kinetics were studied with the help of the Wagner equation. Micrographics analysis has been performed by Scanning electron microscopy (SEM) coupled with energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD) technique. Coated material has been shown better corrosion resistance compared to bare. The low-thickness coating has better corrosion resistance corresponding to both bare and high-thickness.