The synergism of sodium polymetaphosphate-urea on the flammability of a cotton fabric (woven, plain 144 g/m 2 , the number of yarns 21 per 10 mm) has been investigated in this study. After impregnation with suitable individual additives and/or their appropriate admixed formulation onto the fabrics, their flammability has been assessed by using the described procedure. In this study the flame spread tests comply with thermogravimetry's data. Explanation of the synergism with regard to the thermal analysis illustrated moderately effect of sodium polymetaphosphate to show flame-retardancy due to the confinement of phosphate's activity in the polymeric inorganic chain, however this effect increased by using urea.