High-spatial-frequency fringes associated with reflection holographic optical elements are difficult to obtain with currently available recording materials. In this work, holographic reflection gratings were stored in a polyvinyl alcohol/acrylamide photopolymer. This material is formed of acrylamide photopolymer, which is considered interesting material for optical storage applications such as holographic memories. The experimental procedure for examining the high-spatial-frequency response of this material is explained, and the experimental results obtained are presented. With the aim of obtaining the best results, the performance of different material compositions is compared.