Hollow multi-shelled In2S3 hierarchical nanotubes for enhanced photocatalytic oxidative coupling of benzylamine

Cocatalyst-modified In2S3 photocatalysts for C–N coupling of amines integrated with H2 evolution

“…1d, the obvious lattice fringes of 0.277 nm and 0.618 nm are scanned in PdS-In 2 S 3 , corresponding to the (400) and (111) planes of In 2 S 3 , respectively. 15,23,25 Meanwhile, the lattice stripes of 0.324 nm and 0.185 nm belonging to the (200) and (222) planes of PdS, respectively, are also observed in the binary samples. 30,37 Additionally, the results of aberration-corrected high-angle annular dark-field scanning TEM (HAADF-STEM), elemental mapping (Fig.…”

“…[7][8][9][10][11] In contrast, the coproduction of H 2 and value-added imines in one photoredox cycle under anaerobic conditions is a prospective scheme to fully utilize the electrons and holes generated by light for cooperative reactions to simultaneously produce valuable organic chemicals and clean fuel. 12 Indium sulfide (In 2 S 3 ), as a typical III-VI group metal sulfide [13][14][15][16] with an excellent visible light response, 17 low toxicity, 18 stable chemistry, 19 and a suitable band edge position, 20 has been used as photocatalyst for contaminant degradation, 21 CO 2 reduction, 22 organic coupling, 23,24 and H 2 evolution. 25 However, the photocatalytic redox efficiency of blank In 2 S 3 is severely hindered by the absence of catalytically active sites and the rapid recombination of photogenerated charge carriers.…”

Modulation of the Internal Electric Field in Te-Doped Bi2MoO6 Nanosheets: Implication for the Photocatalytic Degradation of Rhodamine B and Photooxidation of Benzylamine

“…In Route B, the generated intermediate BI reacts with O 2 and the • OH radical to form benzylimine (BII), whose reaction with other benzylamine molecules gives intermediate aminal (intermediate BIII). Finally, N -benzylidene-1-benzylamine is obtained by the hole-assisted elimination of the NH 3 group from aminals. − …”

Efficient Photocatalytic Selective Oxidation of Benzylamines over Cobalt Molecular Catalyst Covalently Bonded to Carboxyl Functionalized Carbon Nitride

“…[8] Among various advanced oxidation technologies, photocatalysis is a potential method to achieve high selectivity using O 2 as a green and mild oxidant. Some semiconductor photocatalysts have great potential in the synthesis of imines, such as TiO 2 , [9] In 2 S 3 , [10] BiOX (X = Cl, I, Br), [11] g-C 3 N 4 , [12] triazine photocatalysts. [13,14] In order to ensure the selectivity of imine products through coupling oxidation synthesis, homogeneous molecular catalysts have attracted extensive attention due to their advantages such as high activity and selectivity, tunable structure, and fine control of the active site environment.…”

“…[ 8 ] Among various advanced oxidation technologies, photocatalysis is a potential method to achieve high selectivity using O 2 as a green and mild oxidant. Some semiconductor photocatalysts have great potential in the synthesis of imines, such as TiO 2 , [ 9 ] In 2 S 3 , [ 10 ] BiOX (X = Cl, I, Br), [ 11 ] g‐C 3 N 4 , [ 12 ] triazine photocatalysts. [ 13,14 ]…”