Efficient Photocatalytic Selective Oxidation of Benzylamines over Cobalt Molecular Catalyst Covalently Bonded to Carboxyl Functionalized Carbon Nitride
Chuntao Wang,
Haixia Li,
Yingxin Guo
et al.
Abstract:Photocatalysis is accepted as a promising method for selective oxidative coupling of amine to imine. However, owing to the rapid dehydrogenation of the generated imine intermediate of α‐amino hydrogen to butyronitrile, it remains a huge challenge to fabricate an exquisite catalyst with enhanced conversion and selectivity. Herein, a novel heterogeneous catalyst (Bpy‐CoCl2/CNCOOH) is developed, where carboxyl functionalized carbon nitride (CNCOOH) serves as a substrate material and couples with highly efficien… Show more
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