The specific features of creation of highly thermostable composite materials based on thermostable fillers and binders are examined. There has been some progress in synthesis, modification, and pilot-industrial production of polyimides that satisfy the many-sided requirements of the 21st century. The possibility of assigning products of thermochemical reactions of polymers based on polyacrylonitrile to thermostable organic compounds capable of modifying thermostable binders is discussed. The necessity of theoretical studies of modeling the thermal transformations of the initial products in composite mixtures is demonstrated. The necessity of structural orientation of macrochains of the reacting components for realization of the cocarbonization principle is substantiated.Production of thermostable fibres and materials made from them became an urgent problem in the second half of the 20th century. The successful breakthrough in space was due to solution of a number of materials science problems related to creating new materials capable of working for a long time in extreme conditions.One major problem in science, engineering, and technology is significant expansion of the temperature boundaries of use. Based on a number of indexes, thermostable materials, primarily inorganic materials, have not been totally suited for solving this problem. This primarily concerned the mechanical indexes, high specific density of inorganic insulators, complexity in manufacturing technology, restriction of natural resources, etc. For this reason, the search for new thermostable insulators has been concentrated on creating synthetic materials based on macromolecular compounds. Polymers used as electrical and thermal insulators, frequently combined with inorganic materials, already existed. However, their performance characteristics were only stable up to 100°C.The search for more thermostable polymers began with a study of many organic compounds resistant to high temperatures. New polymers containing different aromatic and heterocyclic compounds were such compounds. Polyoxazoles, polyoxadiazoles, polythiodiazoles, polytriazines, etc., were synthesized. Polymers with condensed rings, i.e., formed by a combination of benzene rings with five-and six-member heterocycles, were of special interest. It was found that the combination of two condensed cyclic structures in such polymers as polybenzimidazoles, polyquinoxalines, etc., increased the stability of the macromolecules to 300°C. Transitioning from laboratory samples to mass-produced industrial articles was very difficult, since it required not only obtaining thermostability of the new polymers but also ensuring their stability in sharp temperature drops, from -190 to +400°C. These polymers simultaneously had to have sufficient strength, flexibility, and elasticity.The subsequent search for organic structures that satisfied these requirements showed that some polymers withstand brief heating to 600°C without marked decomposition, and these compounds in the polymer chain are much better ...