Hochdrucksynthese von K₂PtH₆, einem salzartigen Hydrid mit K₂PtCl₆‐Struktur

Abstract

ZUSCHRIFTEN zP2,4, jeweils ,,dd"); 'JAX = -364, 'JAY = -367, 21, 'JNX = 21, 'JXv = -5 Hz. 6: ABCDE-Spinsystem. 6 = 130.2 (PA=P3 oder P5, ddd), 101.4 (P,=Pl oder P2, dd), 43.0 (Pc=P4, ,,dd"), -1.6 (PD=Pl oder P2, m), -46.6 (PE=P3 oder P5, m): JAB =1.8 (3J oder 'J iiher Fe), -525, 2JcD = -12, 'JCE = -498, JDF = -25 (3J oder *J iiber Fe). 7 : AMM'XX'-Spinsystem. 6 =198.7 (PA, m), 148.7 (P,.,. m), 96.0 (Px, m). ' J AX --507, 'JMM. = -400, 'JMx = -451, ,JAM = -12, 'JMX = 38. 'J,,, = -30). Spektrensimulationsprogramm: PANIC Version 850501.1, Firma Bruker, Karlsruhe. IR(CH,Cl,): 5: \'(CO)[cm-'] =1953 (s, br), 6: 1945 (5, br), 1880 (s), 7 (KBr): 1936 (vs), 1870 (vs), 1835 (vs).[7] a) 3 kristallisiert triklin, P i (Nr. 2); a = 9.127(3). h = 10.5311(3). r = Angew. Chem. 1994, 106, Nr. 10

Lithium Intercalation in Open‐Ended TiS2 Nanotubes

“…For XRD measurements, the Li x TiS 2 nanotubes were coated with paraffin oil, smeared on a glass substrate, and then covered by an adhesive tape to prevent the sample from reacting with oxygen and/or moisture during the measuring process. [16] For TEM observations, the sample grid and specimen holder were prepared in the glove box and transferred to a glove bag (Cheltenham, Model X-27-27 H). During the transfer of the specimen holder to the TEM chamber, special care was taken to minimize the exposure of the sample grid to the atmosphere.…”