In
contrast to the commonly used nondegradable melt-blown nonwovens,
polylactic acid (PLA) melt-blown nonwovens are renewable and biodegradable,
making them very environmentally friendly at their end of life. However,
the strength and toughness of PLA melt-blown nonwovens are generally
insufficient for practical applications. Herein, we report a straightforward
and universal strategy for fabricating PLA melt-blown nonwovens with
superior mechanical properties. In this process, hierarchical controlling
of the high-temperature and high-speed airflow considerably increases
the polymeric chain orientation and crystallization of PLA. High-molecular-weight
(Mw) PLA polymeric chains can be entangled to reduce the negative
effect of excessive polymeric chain orientation on elongation, resulting
in a gain in strength and toughness at the same time. The resulting
PLA melt-blown nonwovens exhibit enhanced strength (1.8 MPa, up by
157%), higher elongation (35.6%, up by 256%), and excellent toughness
(0.59 MJ/m3, up by 788%). Additionally, a plausible tensile
failure mechanism for melt-blown nonwovens is proposed based on the
tensile fracture process. Strikingly, the PLA melt-blown nonwovens
exhibit high particulate matter (PM0.3), removal efficiency
(92.6%), and low pressure drop (12.3 Pa). The successful preparation
of PLA melt-blown nonwovens with superior mechanical properties will
satiate the growing demand for sustainability, personal protection,
and environmental protection.