2016
DOI: 10.1016/j.snb.2016.01.047
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Highly selective fluorescent sensing for fluoride based on a covalently bonded europium mesoporous hybrid material

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Cited by 25 publications
(4 citation statements)
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“…The coordination of pyridine groups with the Eu ions offered much better fluorescence when it interacted with fluoride ions. This could help to have the detection limit of 1.6××10 −9 M for the fluoride ions . In another study, Schiff base complex was immobilized over salicylidene functionalized SBA‐15 materials which were later employed as fluorescent chemosensors and showed a great promise for the selective detection of even a trace amount of Zn ions .…”
Section: Synthesis Of Organo‐functionalized Molecular Sievesmentioning
confidence: 99%
“…The coordination of pyridine groups with the Eu ions offered much better fluorescence when it interacted with fluoride ions. This could help to have the detection limit of 1.6××10 −9 M for the fluoride ions . In another study, Schiff base complex was immobilized over salicylidene functionalized SBA‐15 materials which were later employed as fluorescent chemosensors and showed a great promise for the selective detection of even a trace amount of Zn ions .…”
Section: Synthesis Of Organo‐functionalized Molecular Sievesmentioning
confidence: 99%
“…As shown in Figure 6, it can be seen that, after ultraviolet radiation, the fluorescence of wood is enhanced, which is perhaps due to the fact that, after a long period of radiation exposure, the silane undergoes further hydrolysis and condensation reactions, leading to the formation of an Si-O network structure, which will increase the rigidity of the ligand and reduce the energy loss by non-radiative deactivation [33]. On the contrary, the condensation reaction of organic-inorganic hybrid coatings change the coordination environment of Eu 3+ , which could be reflected by the ratio of 5 D 0 → 7 F 2 (614 nm) transition to 5 D 0 → 7 F 1 (590 nm) transition [34][35][36]. The larger ratio of 5 D 0 → 7 F 2 transition to 5 D 0 → 7 F 1 means that the chemical environment symmetry around the Eu 3+ ion is decreased [37,38].…”
Section: Aging Property and Optical Stabilitymentioning
confidence: 99%
“…胺类等化合物中的 NH 基团能与氟离子发生配位作 用 [12] , 并能进一步发生去质子化 [13] , 故可被广泛地用作 氟离子的识别基团. 按照作用位点的多少, 此类氟离子 探针可分为单位点型和多位点型(其含有 2 个或 2 个以 上的去质子化作用位点).…”
Section: Nh 类的去质子化unclassified