Highly robust, novel aluminum counter cation-based monophosphate tungsten bronze electro-catalysts for oxygen evolution in acidic solution

Hossain, Imran; Debnath, Tapas; Mollah, M. Yousuf A.; Susan, Md. Abu Bin Hasan; Islam, Md. Mominul

doi:10.1039/d1ra00699a

Cited by 5 publications

(1 citation statement)

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“…3d) that actually occurs due to the presence of a high density of low-coordinated atoms, steps, edges, and kinks in the microstate of a material. In POM, tungsten may exist as a low valent state in the presence of an electron-rich atom/group, 92 with a diameter of ca. 46 Å (4.6 nm 93 ).…”

Section: Resultsmentioning

confidence: 99%

Polyoxometalate Archetype-Boosted Stability and Charge Storage of 2D Graphene Nanosheets

Musa

Islam

Susan

et al. 2023

ECS J. Solid State Sci. Technol.

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In this study, the potential of impregnation of phosphotungstic acid (PTA), a polyoxometalate, in enhancing specific capacitance (Csp) and diminishing the well-known restacking phenomenon of graphene nanosheets was explored. Graphene nanosheets were prepared chemically from graphite powder through the formation of graphene oxide (GO) and then the subsequent reduction of GO to the reduced GO (rGO). Impregnation of PTA in rGO-PTA (rGP) composites was carried out by simply dispersing rGO and PTA derived from tungstic acid. Scanning electron microscopy, X-ray diffraction analysis, UV-vis reflectance spectroscopy, and Fourier-transform infrared spectroscopy were used to analyze the elemental composition, microstates, and morphology of the composites. The charge-storing capacity and stability of the prepared rGP composites casted on a graphite electrode were examined with cyclic voltammetric, chronopotentiometric, and electrochemical impedance techniques. The effect of ions on the charging capacity of the electrodes was verified using electrolytes with different ion sizes. About 100% enhancement of Csp of rGO was achieved by impregnating rGP composites with only 1% PTA and ca. 87% capacitance retention for 2000 charging-discharging cycles were observed.

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Section: Resultsmentioning

confidence: 99%