The
formation of nanoscale junctions among nanoparticles in self-assembled
nanostructures is crucial for improving both interfacial conductivity
and structural integrity. However, the inherent reliance on weak van
der Waals forces to hold nanoparticles together poses challenges in
developing commercially viable devices due to their inefficient carrier
transport characteristics. This study presents the successful integration
of carbon nanotubes (CNTs) into highly porous nanomicrocluster arrays
of ZnO, resulting in the formation of cohesive and crack-free highly
porous ZnO/CNT heterojunction films. This integration marks a significant
improvement in UV photodetection performance, demonstrating a record-high
photocurrent to dark current ratio of 3.3 × 106 and
an exceptional responsivity of 18.5 A/W at a low bias of 0.5 V and
under an ultra low light density of 25 μW/cm2. These
findings underscore the efficacy of this high-performance structure
as a versatile and scalable platform technology for the rapid, cost-effective
fabrication of hybrid photodetectors in wearable and portable devices.