Highly effective activation of aryl chlorides for Suzuki coupling in aqueous media using a ferrocene-based Pd(II)–diimine catalyst

Hanhan, Murat Emre; Martínez‐Máñez, Ramón; Ros‐Lis, José V.

doi:10.1016/j.tetlet.2012.02.102

Cited by 25 publications

(10 citation statements)

References 23 publications

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“…The use of diimine or pyridylimine ligands, in lieu of phosphine ligands, has major benefits, such as simple synthetic procedures, easy management and easy tuning of the electronic and steric properties of the final catalysts. In this context, [68] have reported the MW assisted SMC, in aqueous media, of different boronic acids with aryl chlorides using a ferrocene-containing Pd(II)-diimine complex as the catalyst. The use of the air-stable diimine ligand, which bears two ferrocene units, was observed to be powerful for SMC reactions due to the sterically demanding character of the ligand and the electron-rich properties of the ferrocene fraction.…”

Section: Ligands In Mw-assisted Smcmentioning

confidence: 99%

Eco-Friendly Physical Activation Methods for Suzuki–Miyaura Reactions

et al. 2017

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Eco-compatible activation methods in Suzuki-Miyaura cross-coupling reactions offer challenging opportunities for the design of clean and efficient synthetic processes. The main enabling technologies described in the literature are microwaves, ultrasound, grinding (mechanochemistry) and light. These methods can be performed in water or other green solvents with phase-transfer catalysis or even in solventless conditions. In this review, the authors will summarize the progress in this field mainly from 2010 up to the present day.

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Section: Ligands In Mw-assisted Smcmentioning

confidence: 99%

Eco-Friendly Physical Activation Methods for Suzuki–Miyaura Reactions

et al. 2017

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“…Hanhan et al [84] described an efficient method for the synthesis of sterically hindered ortho-substituted biaryls by Suzuki-Miyaura coupling reaction of unactivated aryl chlorides and heterocyclic chlorides with boronic acid, employing ferrocene-containing Pd(II)-diimine complex as a catalyst (Figure 7). A small amount of catalyst (0.1%) was found highly effective.…”

Section: Ferrocene-based Palladium Catalystmentioning

confidence: 99%

“…It was anticipated that with the use of this ligand magnetically interesting 3d/4f heterobimetallic compounds could be produced, where the 3d metal ion has magnetic anisotropy, such as Co(II) or Ni(II). FIGURE 6 Asymmetric catalysis of ferrocenyl ligands [83] FIGURE 7 Suzuki-Miyaura coupling reaction [84] FIGURE 8 Molecular structure of LZn(μ-OAc)Dy(NO 3 ) 2 complex [85]…”

Section: Ferrocene-based Compartmental Ligandsmentioning

confidence: 99%

Recent advances in the synthesis, biological activities and various applications of ferrocene derivatives

Larik

Saeed

Fattah

et al. 2016

Applied Organom Chemis

123

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Ferrocene derivatives constitute an important class of organometallic compounds with not only an extensive range of biological activities but also diverse industrial as well as material science applications. These stimulating features of ferrocene derivatives spurred us to review the recent advances in synthesis methods and biological and other applications reported in the latest literature. An effort has been made to summarize the recent developments in synthetic methods providing access to ferrocene scaffolds and the useful medicinal and material applications, including agricultural, catalytic, polymer, conducting, redox mediating, ferrocenyl stationary phase, rocket propellant and ion sensing applications. Ferrocene‐based bulky metallocenes are also discussed.

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“…An α-diimine ligands with different electronic property, rigidity and steric hindrance has been widely synthesized due to their significant applications in catalysis, coordination chemistry and carbene chemistry (Grasa et al, 2001;Williams et al, 2008;Hanhan et al, 2012;Partyka, 2011;Yuan et al, 2012). As part of our research efforts focused on developing ligands and organic catalysts, a novel series of imine derivatives were synthesized.…”

Section: Commentmentioning

confidence: 99%