1997
DOI: 10.1116/1.589306
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Highly anisotropic silicon reactive ion etching for nanofabrication using mixtures of SF6/CHF3 gases

Abstract: A novel highly anisotropic room-temperature process for silicon etching, using mixtures of SF6 and CHF3 gases is presented. The etch rate, selectivity, dc bias voltage and anisotropy as a function of the reactive ion etching conditions (mixture composition, pressure and rf power) are discussed. Excellent anisotropy combined with clean, damage-free surfaces and etching uniformity and reproducibility have been achieved. It was thus possible to fabricate free standing silicon wires with diameter less than 50 nm a… Show more

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Cited by 32 publications
(11 citation statements)
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“…The Cr grating pattern is transferred into the Si substrate by a two-step etch process that relies on the formation of polymer-based sidewall passivation to achieve an anisotropic etch. 19 The first etch step uses CHF 3 and SF 6 ͑35and 5-SCCM gas flow rates͒ and the second uses just CF 4 ͑40 SCCM͒. In both cases the rf power is 125 W and the chamber pressure is 10 mTorr.…”
Section: B Fabricationmentioning
confidence: 99%
“…The Cr grating pattern is transferred into the Si substrate by a two-step etch process that relies on the formation of polymer-based sidewall passivation to achieve an anisotropic etch. 19 The first etch step uses CHF 3 and SF 6 ͑35and 5-SCCM gas flow rates͒ and the second uses just CF 4 ͑40 SCCM͒. In both cases the rf power is 125 W and the chamber pressure is 10 mTorr.…”
Section: B Fabricationmentioning
confidence: 99%
“…Different methods have been developed for the fabrication of SiNWs either by Si etching [12,21,22] or by Si nanowire synthesis [1,23]. Among them, the technique of metal-assisted chemical etching [MACE] [24-29] has gained an increasing interest in the last years due to its simplicity and the high crystalline quality of the obtained SiNWs, resulting from etching of the single crystalline Si material.…”
Section: Introductionmentioning
confidence: 99%
“…Moreover, etching parameters were selected such as to provide both anisotropic as well as isotropic etching of PS, by choosing conditions similar to those applied to c-Si etching. In specific, etching in pure SF 6 that provides nearly isotropic etching of c-Si [6], as well as etching in fluorocarbon-containing plasmas (SF 6 /C 4 F 8 , SF 6 /CHF 3 ) [7,8] that ensure anisotropic etching of c-Si are examined. The gas composition SF 6 /C 4 F 8 was used in the pulsed mode (like in a Bosch process [7]), with each gas being introduced in the reactor in cycles of 7 sec/3 sec duration for SF 6 and C 4 F 8 , correspondingly.…”
Section: Methodsmentioning
confidence: 99%