Novel scheelite-type [Ca 0.55 (Nd 1-x Bi x) 0.3 ]MoO 4 (0.2 ≤ x ≤ 0.95) ceramics were prepared using the solid-state reaction method. According to the X-ray diffraction data, a solid solution was formed in 0.2 ≤ x ≤ 0.95 and all the samples belong to pure scheelite phase with the tetragonal structure. As revealed by Raman spectroscopy, the number of vibrational modes decreased with the increase in x value, which further indicated that Bi 3+ ions occupied A-site of scheelite structure. As the x value increased, the sintering temperature decreased from 740°C to 660°C; the permittivity increased from 12.6 to 20.3; the Qf value first decreased slightly and gradually remained stable. Based on the infrared reflectivity spectrum analysis, the calculated permittivity derived from the fitted data shared the same trend with the measured value. The [Ca 0.55 (Nd 0.05 Bi 0.95) 0.3 ]MoO 4 ceramic sintered at 660 °C attained a near-zero value temperature coefficient ~τ f (−7.1 ppm/°C) and showed excellent microwave dielectric properties with a ɛ r ~ 20.3 and a Qf ~ 33 860 GHz, making this system a promising candidate in the ultralow temperature cofired ceramic (ULTCC) technology. K E Y W O R D S infrared spectra, low-sintering, LTCC, Raman spectra 1 | INTRODUCTION Microwave device is an important part of the modern wireless communication system, with the 5th generation wireless systems coming. The investigation of microwave ceramic is drawing more and more attention. 1 Meanwhile, a series of new materials manufacturing process, such as the low-temperature cofired ceramic (LTCC) technology and This is an open access article under the terms of the Creat ive Commo ns Attri bution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.