“…The materials examined have compositions near that of stoichiometric Li20"A1203"2SiO2, i.e., LiA1SiO~. Materials of this stoichiometry form the basis of the class of materials which, when in crystalline form, exhibit the /3-eucryptite structure (1)(2)(3)(4)(5)(6)(7)(8)(9)(10)(11). These materials are of interest for high temperature solid electrolyte applications ( 12), e.g., thermal batteries (13), because of the combined characteristics of low thermal expan-Key words: solid electrolytes, lithium ion conductors, ionic conductivity, lithium aluminosilicate glass and glass-ceramic, fl-eueryptite structure.…”