“…Recently, a helicon plasma ion source generated a high monatomic fraction of 94% even with a low RF power of 1.3 kW, and numerical simulations failed to explain its high monatomic fraction fully with its high plasma density and raised the existence of energetic electrons in the helicon plasmas as a possible reason. 1 On the other hand, chamber wall materials such as quartz were reported to increase the monatomic fraction by decreasing the recombination coefficient 2 or increasing the plasma density with a higher secondary electron emission coefficient and enhanced ion confinement with an alumina layered plasma boundary, 3,4 which was utilized in ECR (electron cyclotron resonance) ion sources not only as a wall material but also as a plasma electrode material. However, increases in the monatomic fraction in hydrogen plasmas with a dielectric chamber wall are not clearly understood whether they are due to the increase in the plasma density by a higher secondary emission coefficient and enhanced ion confinement, or due to a lower recombination coefficient of dielectric materials.…”