“…Bands were eliminated when systematic displacements or misassignments were made apparent by the term value calculations. For example an incompatibility in the (2,3) band of the B-X System was found when testing the data of Dick et al [22] together with the data of Benesch et al [25]. Differences between the observed lines and the reconstructed ones are systematically too large.…”
Section: Determination Of the Term Values And Of The Parametersmentioning
confidence: 97%
“…A-X System: The (O,O), (1,0), (2,0), (3,0), (3, 11, (4, 11, (4,2) and (5,2) bands of Benesch et al [25].…”
Section: Determination Of the Term Values And Of The Parametersmentioning
confidence: 99%
“…They cover the spectral region from 445 to extended to higher vibrational levels [ 10,111 and entirely new 565 m. many cases the spin doublets were resolved at systems [12-151 of N: were observed. More recently new lower N values than before and the analysis was extended to investigations [16][17][18] or reinvestigations [19][20][21][22][23][24][25][26] have been higher rotational quantum numbers so that new perturbations published. Lofthus' critical summary [271 has been revised by could be observed.…”
Twenty-five bands of the First Negative System, B 2Σu+ - X 2Σg+, of the Nitrogen Molecule Ion N2+ have been analysed or reanalysed. The previous analysis of the (7, 10) band is found to be incorrect. Molecular constants for the X 2Σg+, A 2Πu, B 2Σu+ and C 2Σu+ states obtained with the term value approach from seventy-one bands are presented.
“…Bands were eliminated when systematic displacements or misassignments were made apparent by the term value calculations. For example an incompatibility in the (2,3) band of the B-X System was found when testing the data of Dick et al [22] together with the data of Benesch et al [25]. Differences between the observed lines and the reconstructed ones are systematically too large.…”
Section: Determination Of the Term Values And Of The Parametersmentioning
confidence: 97%
“…A-X System: The (O,O), (1,0), (2,0), (3,0), (3, 11, (4, 11, (4,2) and (5,2) bands of Benesch et al [25].…”
Section: Determination Of the Term Values And Of The Parametersmentioning
confidence: 99%
“…They cover the spectral region from 445 to extended to higher vibrational levels [ 10,111 and entirely new 565 m. many cases the spin doublets were resolved at systems [12-151 of N: were observed. More recently new lower N values than before and the analysis was extended to investigations [16][17][18] or reinvestigations [19][20][21][22][23][24][25][26] have been higher rotational quantum numbers so that new perturbations published. Lofthus' critical summary [271 has been revised by could be observed.…”
Twenty-five bands of the First Negative System, B 2Σu+ - X 2Σg+, of the Nitrogen Molecule Ion N2+ have been analysed or reanalysed. The previous analysis of the (7, 10) band is found to be incorrect. Molecular constants for the X 2Σg+, A 2Πu, B 2Σu+ and C 2Σu+ states obtained with the term value approach from seventy-one bands are presented.
“…It is therefore to be expected that the molecular constants of such a series also converge to the constants of the ionic state. In Table IX the constants of the ground state and the first excited state of the molecular ion [45][46][47][48] are listed. Based on the rotational B parameter, a first crude assignment can be made on the character of the excited state.…”
Highly excited states of gerade symmetry in molecular nitrogen have been investigated in a resonance-enhanced XUV+Vis (extreme ultraviolet+visible) transition scheme. Nineteen bands have been observed, of which only four involve known states [k 1Πg (v=1), x 1Σg− (v=2), and y 1Πg (v=1,2)], albeit in new systems. Three of the newly observed states have been assigned as y 1Πg (v=3) and k 1Πg (v=2,3). Level energies are determined with an accuracy of ≈0.20 cm−1.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.