The 2.7 μm emission properties of Er 3+ /Nd 3+ -codoped fluorotellurite glasses were investigated in the present work. The thermal stability, refractive index, absorption and transmission spectra, and emission spectra were measured and investigated. The 2.7 μm emission in Er 3+ /Nd 3+ -codoped fluorotellurite glasses was enhanced with the increase of fluorine ions. The Judd−Ofelt analysis based on absorption spectra was performed in order to determine the Judd−Ofelt intensity parameters Ωt (t = 2, 4, 6), spontaneous emission probability, radiative lifetime and branching ratios of Er 3+ : 4 I 11/2 → 4 I 13/2 transition. It is found that the Er 3+ /Nd 3+ -codoped fluorotellurite glass possesses a lower spontaneous transition probability A (58.95 s −1 ) but a higher branching ratio β (15.72%) corresponding to the stimulated emission of Er 3+ : 4 I 11/2 → 4 I 13/2 transition. Additionally, the transmittance was also tested and reached a maximum when the molar concentration of ZnF 2 is 15%. The presence of fluorine ions greatly decreases the population of OH groups, which affects the 2.7 μm emission effectively by means of decreasing the rate of energy transfer to impurities (e.g., OH groups).
I. INTRODUCTIONThe investigation of solid state lasers operating in the midinfrared wavelength region (2−5 μm) has been taken widely in the past few years. Many potential applications, such as medical lasers, sensing, military counter-measures as well as light detection and ranging (LIDAR) were offered by the devices operating in the mid-infrared wavelength region. 1−3 Light sources in the 2.7 μm region are of great interest owing to the strong absorption by water in this spectral region. Despite the laser characteristics of the 2.7 μm (Er 3+ : 4 I 11/2 → 4 I 13/2 selfterminating transition) are not satisfactory, Er 3+ is an important candidate to provide 2.7 μm emission. Fortunately, codoping of Nd 3+ has been demonstrated to enhance the 2.7 μm emission. 4,5 In order to achieve strong emission at the 2.7 μm region, the main effort so far has been concentrated on the Er 3+ -doped fluoride and chalcogenide glasses because of their low phonon energy which decreases the rate of nonradiative transitions. 6,7 However, the applications of fluoride and chalcogenide glasses are limited due to their poor chemical durability and thermal stability. The oxide and oxyfluoride glasses possess better characteristics in mechanical strength, thermal stability, and chemical durability than fluoride and chalcogenide glasses and the successful observation of 2.7 μm emission from oxide and oxyfluoride glasses host stand only in a few glass systems up to now. 4,8−10 Because of the low phonon energy and good physicochemical properties of tellurite glasses, it is considered to be a new candidate material for 2.7 μm emission. While, the