High performance red phosphorus electrode in ionic liquid-based electrolyte for Na-ion batteries

Dahbi, Mouad; Fukunishi, Mika; Horiba, Tatsuo; Yabuuchi, Naoaki; Yasuno, Shinji; Komaba, Shinichi

doi:10.1016/j.jpowsour.2017.07.089

Cited by 52 publications

(42 citation statements)

References 39 publications

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“…Moreover, this increased efficiency is coupled with the fact that the IL electrolyte displayed a higher capacity at the elevated temperature, thus showing the use of ILs could be a way to inure the battery from the deleterious effects of temperature swings. Komaba and co‐workers also showed the effectiveness of a N ‐methyl‐ N‐ propylpyridinium‐bisfluorosulfonylamide (MPPFSA) IL electrolyte with a red phosphorus anode . Following 80 cycles, the capacity retention of the anode with the IL electrolyte was of 93%, while over the same duration the EC:DEC electrolyte only showed a capacity retention of 30%, showing the effectiveness of IL electrolyte goes beyond just carbon materials.…”

Section: Electrolytes For Nibsmentioning

confidence: 98%

Electrolytes, SEI Formation, and Binders: A Review of Nonelectrode Factors for Sodium‐Ion Battery Anodes

Bommier

2018

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249

181

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Through intense effort in recent years, knowledge of Na-ion batteries has been advanced significantly, pertaining to electrodes. Often, such progress has been accompanied by using a convenient choice of electrolyte or binder. Nevertheless, it has been witnessed that "external" factors to electrodes, such as electrolytes, solid electrolyte interphase, and binders, affect the functions of electrodes profoundly. And generally, certain types of electrodes favor some electrolytes or binders. With a rapidly increasing number of publications in the area, trends in terms of electrolytes and binders are possibly exploitable. Unfortunately, the field has yet to see a review article that devotes itself to these nonelectrode aspects of Na-ion batteries. Here, the gap is filled by conducting a comprehensive review of these nonelectrode external factors, especially by looking into their correlation with electrochemical properties, such as cycle life, and first cycle coulombic efficiency. Not only are the representative reports reviewed, but also quantitative analyses on the database that are constructed are provided. With such analyses, some new data-driven perspectives are postulated, which are of great value to the community.

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Section: Electrolytes For Nibsmentioning

confidence: 98%

Electrolytes, SEI Formation, and Binders: A Review of Nonelectrode Factors for Sodium‐Ion Battery Anodes

Bommier

2018

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249

181

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“…[ 101 ] The same electrolyte composition was employed in sodium cells in combination with a Sb 2 S 3 /graphene anode material, showing superior performance compared to conventional carbonate‐based electrolyte. [ 102 ] Owing to its superior properties, Pyr 13 FSI–NaFSI has been applied for SIBs by several other research groups in different cell configurations, [ 103–107 ] nevertheless it is interesting to note the effects that the salt anion has on the performance and accordingly there is certainly much room to improve these IL‐based electrolytes for future applications. Furthermore, while there has been significant investigation of the behavior of the electrode/electrolyte interphase in organic electrolytes, as discussed above, there is a lesser understanding of the interphase in the IL‐based systems.…”

Section: Electrolytes For Na‐based Rechargeable Batteriesmentioning

confidence: 99%

Electrolytes and Interphases in Sodium‐Based Rechargeable Batteries: Recent Advances and Perspectives

Eshetu

Elia

Armand

et al. 2020

Advanced Energy Materials

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277

258

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technologies. Unlike lithium, whose market is already very tight, sodium mineral deposits are almost infinite, evenly distributed worldwide, much easier to extract and thereby attainable at low cost. [1][2][3][4] If the realization of Na-rechargeable batteries could be practically possible, there will be nearly three orders of magnitude relaxation in the constraints on lithium-based resources, accompanied by sustainability, improved environmental benevolence, and cost reduction ( Table 1). Even more appealing is the possible use of the widely available and lighter aluminum, rather than copper, as negative current collector and hard carbon from renewable sources instead of graphite for the negative electrode. Finally, the stability of sodium-ion batteries (SIBs) in the fully discharged state would significantly enhance the safety associated with the shipment of large-format SIBs worldwide.These beneficial features of sodiumbased cells revived the research work on Na-based rechargeable batteries and accordingly captured the attention of both the academic research and industry sectors. However, similar to LIB, most of the research work in Na-based batteries have focused on the development and elaboration of negative and positive For sodium (Na)-rechargeable batteries to compete, and go beyond the currently prevailing Li-ion technologies, mastering the chemistry and accompanying phenomena is of supreme importance. Among the crucial components of the battery system, the electrolyte, which bridges the highly polarized positive and negative electrode materials, is arguably the most critical and indispensable of all. The electrolyte dictates the interfacial chemistry of the battery and the overall performance, having an influence over the practical capacity, rate capability (power), chemical/thermal stress (safety), and lifetime. In-depth knowledge of electrolyte properties provides invaluable information to improve the design, assembly, and operation of the battery. Thus, the full-scale appraisal of both tailored electrolytes and the concomitant interphases generated at the electrodes need to be prioritized. The deployment of large-format Na-based rechargeable batteries also necessitates systematic evaluation and detailed appraisal of the safety-related hazards of Na-based batteries. Hence, this review presents a comprehensive account of the progress, status, and prospect of various Na + -ion electrolytes, including solvents, salts and additives, their interphases and potential hazards.

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“…Park et al [50] fabricated the BP material through transforming commercially available amorphous RP into orthorhombic BP using the high-energy mechanical milling technique at ambient temperature and pressure. [198,199] Accordingly, Qian et al [43] SIBs [177] a) The stable PC bonds generated during the milling process would be able to prevent the structure of BP/carbon composite from destruction upon cycling.…”

Section: High-energy Mechanical Millingmentioning

confidence: 99%

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Wei

Zhang

et al. 2018

Advanced Energy Materials

163

128

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High‐performance and lost‐cost lithium‐ion and sodium‐ion batteries are highly desirable for a wide range of applications including portable electronic devices, transportation (e.g., electric vehicles, hybrid vehicles, etc.), and renewable energy storage systems. Great research efforts have been devoted to developing alternative anode materials with superior electrochemical properties since the anode materials used are closely related to the capacity and safety characteristics of the batteries. With the theoretical capacity of 2596 mA h g−1, phosphorus is considered to be the highest capacity anode material for sodium‐ion batteries and one of the most attractive anode materials for lithium‐ion batteries. This work provides a comprehensive study on the most recent advancements in the rational design of phosphorus‐based anode materials for both lithium‐ion and sodium‐ion batteries. The currently available approaches to phosphorus‐based composites along with their merits and challenges are summarized and discussed. Furthermore, some present underpinning issues and future prospects for the further development of advanced phosphorus‐based materials for energy storage/conversion systems are discussed.

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High performance red phosphorus electrode in ionic liquid-based electrolyte for Na-ion batteries

Cited by 52 publications

References 39 publications

Electrolytes, SEI Formation, and Binders: A Review of Nonelectrode Factors for Sodium‐Ion Battery Anodes

Electrolytes, SEI Formation, and Binders: A Review of Nonelectrode Factors for Sodium‐Ion Battery Anodes

Electrolytes and Interphases in Sodium‐Based Rechargeable Batteries: Recent Advances and Perspectives

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

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