High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization

Mussel‐inspired double cross‐linked interpenetrating network with unique mechanical properties using di‐diol complexation

“…Fabricating high‐performing polymer‐based composite is necessary to bridge the inherent gap between physics, chemistry, and polymer and explore engineering applications. [ 1 ] In the recent past, the incorporation of carbonaceous nanostructured materials such as graphene, graphene oxide, Carbon Nanotubes (CNTs), cellulose nanofiber, and so forth, bearing high aspect ratio, in the polymer matrix has gained popularity as an effective nano‐reinforcement for the strategic formulation of stable polymer nanocomposite. [ 1 ] However, the maintenance of mechanical integrity is an inevitable requirement for the design of such high‐performance polymer nanocomposites.…”

“…[ 1 ] In the recent past, the incorporation of carbonaceous nanostructured materials such as graphene, graphene oxide, Carbon Nanotubes (CNTs), cellulose nanofiber, and so forth, bearing high aspect ratio, in the polymer matrix has gained popularity as an effective nano‐reinforcement for the strategic formulation of stable polymer nanocomposite. [ 1 ] However, the maintenance of mechanical integrity is an inevitable requirement for the design of such high‐performance polymer nanocomposites. Therefore, several attempts have been made to develop high‐strength and easily processable polymer nanocomposites, infusing carbonaceous nanofillers in the polymer matrix.…”

“…The term “mussel‐inspired” in the title, demonstrates how an advanced and highly multifunctional material can be engineered and developed using MIMs (mussel‐inspired materials). However, for target‐specific applications requiring mechanical strength several carbonaceous nanofiller like graphene oxide, [ 1 ] CNT, CNF, and so forth, have been incorporated into a neat PVA matrix. [ 1 ]…”

“…The term "mussel-inspired" in the title, demonstrates how an advanced and highly multifunctional material can be engineered and developed using MIMs (mussel-inspired materials). However, for target-specific applications requiring mechanical strength several carbonaceous nanofiller like graphene oxide, [1] CNT, CNF, and so forth, have been incorporated into a neat PVA matrix. [1] As discussed earlier, the fabrication of suitable IPNs is advantageous upon addition of one component while maintaining the key attributes of another which in turn purposefully serve the enhancement of mechanical strength.…”

“…However, for target-specific applications requiring mechanical strength several carbonaceous nanofiller like graphene oxide, [1] CNT, CNF, and so forth, have been incorporated into a neat PVA matrix. [1] As discussed earlier, the fabrication of suitable IPNs is advantageous upon addition of one component while maintaining the key attributes of another which in turn purposefully serve the enhancement of mechanical strength. [11,12] In line with this, poly(vinyl alcohol)/polydopamine (PDA) sequential IPN via in situ polymerization of dopamine in PVA matrix has been designed.…”