and aquifers has compelled researchers to re-design approaches for the treatment of these sources as well as consider newer alternatives to meet the current demands. [3,4] In this regard, desalination has shown immense potential to cater to the worldwide water crisis. [5][6][7] Among current desalination strategies, forward osmosis (FO) offers a more significant advantage with low energy consumption, operation costs, lower driving pressures, efficient rejection characteristics, and reduced fouling of membranes among the current pressure-driven processes. [6,[8][9][10] While polyamide thin film nanocomposites (TFC) are the traditional membranes used in forward osmosis applications, recently, researchers have started to explore 2D materials-based membranes for forward osmosis desalination applications. [7,11] Traditional thin film nanocomposite is substrate dependent, the polyamide thin film layer (≈10-400 nm in thickness) is bound to a porous ultrafiltration membrane substrate and nonwoven fabric support and has permeability-selectivity trade-off to maintain the desired performance. [12,13] Also, these membranes require high pumping and frequent replacements, which adds up costs and is vulnerable to fouling and chlorine attack. [14,15] Free-standing 2D assemblies are 2D nanoparticle systems are vacuum filtered, self-assembled, or cast and stripped from the substrate and offer unique characteristics like the minimal effect of the substrate, facile transferability, flexibility, and high permeability. [16] The free-standing membranes with sub-nanometer exclusion characteristics (interlayer spacing between sheets acting as sieves for the size-based exclusion of ions) are, generally, graphene-based derivatives or transition metal dichalcogenides like MoS 2 . [11,[17][18][19] The critical distinguishing traits garnering the interest of the researchers is its excellent salt rejection, chlorine tolerance, and good water flux compared to thin film composites. [7] Among the previously mentioned 2D materials, hexagonal BN (h-BN) has shown to be a potential contender with the lowest interplanar spacing of 3.34 Å and has structured carbon lattices based crystalline arrangements analogous to graphite. [20,21] Due to its hexagonal arrangement with few layers, it is also called white graphene or non-carbon graphene. [22] Herein, a facile "matrix-free" thin film membrane strategy is reported that exploits polymer brushes grafted hydroxyl-functionalized hexagonal boron nitride nanosheets (h-BNOH) toward forward osmosis desalination and dye rejection application. The functionalized nanosheets are characterized using Fourier transform infrared spectroscopy (FTIR), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Nuclear magnetic resonance (NMR), UV-visible spectrophotometry, and thermogravimetric analysis (TGA). Covalently functionalized nanosheets of poly methyl methacrylate (PMMA) termed as boron nitride grafted PMMA (BN-g-PMMA) obtained via RAFT polymerization are deployed toward "matrix-free" nan...