Abstract:Abstract— A high‐rate sputtering‐deposition process for MgO thin films for PDP fabrication was recently developed. The deposition rate of the MgO thin film was about 300 nm/min which shows the possibility of production‐line application. The MgO film deposited in this work has a higher density than that of other deposition processes such as electron‐beam deposition and shows good discharge characteristics including firing voltage and discharge formation. These were achieved by controlling the stoichiometry and/… Show more
“…In this study, we adapted a hot-cathode sputtering method. 11 Figure 1 is a schematic diagram of the hot-cathode sputtering method. In this method, we inserted a quartz plate between the cathode electrode and the target to increase the target temperature and used powder materials as the sputtering target.…”
Section: Methodsmentioning
confidence: 99%
“…2, the temperature of the powder target is increased by the heat-insulation effect and the target material is deposited by sublimation with red heat in addition to the collision with Ar ions. 11 Therefore, in this method, Sr is preferentially deposited due to its high saturation vapor pressure compared with that of Zr. In this study, the background pressure was 4 × 10 -3 Pa, RF power was 600 W, and working pressure during deposition was 0.3 Pa. SrO and SrZrO 3 powder were used as targets.…”
MgO thin film is currently used as a surface protective layer for dielectric materials because MgO has a high resistance during ion sputtering and exhibits effective secondary electron emission. The secondary-electron-emission coefficient γ of MgO is high for Ne ions; however, it is low for Xe ions. The Xe content of the discharge gas of PDPs needs to be raised in order to increase the luminous efficiency. Thus, the development of high-γ materials replacing MgO is required. The discharge properties and chemical surface stability of SrO containing Zr (SrZrO) as the candidate high-γ protective layer for noble PDPs have been characterized. SrZrO films have superior chemical stability, especially the resistance to carbonation because of the existence of a few adsorption sites due to their amorphous structure. The firing voltage is 60 V lower than that of MgO films for a discharge gas of Ne/Xe = 85/15 at 60 kPa. FIGURE 1 -Schematic diagram of the hot-cathode sputtering system. The powder target and thermal insulator between the target and cathode electrode were used in order to increase the target temperature.
“…In this study, we adapted a hot-cathode sputtering method. 11 Figure 1 is a schematic diagram of the hot-cathode sputtering method. In this method, we inserted a quartz plate between the cathode electrode and the target to increase the target temperature and used powder materials as the sputtering target.…”
Section: Methodsmentioning
confidence: 99%
“…2, the temperature of the powder target is increased by the heat-insulation effect and the target material is deposited by sublimation with red heat in addition to the collision with Ar ions. 11 Therefore, in this method, Sr is preferentially deposited due to its high saturation vapor pressure compared with that of Zr. In this study, the background pressure was 4 × 10 -3 Pa, RF power was 600 W, and working pressure during deposition was 0.3 Pa. SrO and SrZrO 3 powder were used as targets.…”
MgO thin film is currently used as a surface protective layer for dielectric materials because MgO has a high resistance during ion sputtering and exhibits effective secondary electron emission. The secondary-electron-emission coefficient γ of MgO is high for Ne ions; however, it is low for Xe ions. The Xe content of the discharge gas of PDPs needs to be raised in order to increase the luminous efficiency. Thus, the development of high-γ materials replacing MgO is required. The discharge properties and chemical surface stability of SrO containing Zr (SrZrO) as the candidate high-γ protective layer for noble PDPs have been characterized. SrZrO films have superior chemical stability, especially the resistance to carbonation because of the existence of a few adsorption sites due to their amorphous structure. The firing voltage is 60 V lower than that of MgO films for a discharge gas of Ne/Xe = 85/15 at 60 kPa. FIGURE 1 -Schematic diagram of the hot-cathode sputtering system. The powder target and thermal insulator between the target and cathode electrode were used in order to increase the target temperature.
“…Results in agreement with those just mentioned can also be observed for 3D porous scaffolds (Table 2); a lower magnesium content in comparison with the corresponding flat samples can be noted, which is closely related to the analytical problems that the morphology and structure of these porous samples can cause. The different outcomes obtained by varying the feed composition are attributable to the impact of the latter on the RF sputter process from the MgO target, which is known to affect the sputtering yield [37][38][39][40][41]. It is possible to conclude that under the experimental conditions used in this work, H 2 O feed shows a lower capacity than Ar and Ar/H 2 O to sputter Mg from the target, while the H 2 feed exhibits a higher ability to sputter the same material compared with Ar and Ar/H 2 mixtures.…”
Section: Chemical and Physical Characterization Of Pcl Flat Samples Amentioning
confidence: 99%
“…As a result, a decrease in the sputter rate can occur because the binding energy of the compounds is much higher than that of pure metals. On the contrary, when H 2 is used as a reactive gas, it can promote the etching of the oxygen present on the target and the formation of metallic Mg, which can be easily sputtered due to its higher sputter rate compared to MgO [37][38][39][40][41]. In fact, after the sputtering process performed with H 2 , the color of the target's surface turns grayish, which is indicative of the formation of metallic Mg.…”
Section: Chemical and Physical Characterization Of Pcl Flat Samples Amentioning
confidence: 99%
“…In Figure 7, the viability data obtained for Saos-2 cells grown on the three types of scaffolds with different culture times (17,40, and 88 h) are reported. This can be attributed to the fact that the MTT values are too low to be able to perceive a difference in cell viability on different scaffolds.…”
Magnesium plays a pivotal role in the formation, growth, and repair of bone tissue; therefore, magnesium-based materials can be considered promising candidates for bone tissue engineering. This study aims to functionalize the surfaces of three-dimensional (3D) porous poly-ε caprolactone (PCL) scaffolds with magnesium-containing coatings using cold plasma-assisted deposition processes. For this purpose, the radiofrequency (RF) sputtering of a magnesium oxide target was carried out in a low-pressure plasma reactor using argon, water vapor, hydrogen, or mixtures of argon with one of the latter two options as the feed. Plasma processes produced significant differences in the chemical composition and wettability of the treated PCL samples, which are tightly related to the gas feed composition, as shown by X-ray photoelectron spectroscopy (XPS) and water contact angle (WCA) analyses. Cytocompatibility assays performed with Saos-2 osteoblast cells showed that deposited magnesium-containing thin films favor cell proliferation and adhesion on 3D scaffold surfaces, as well as cell colonization inside them. These films appear to be very promising for bone tissue regeneration.
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