High performance membranes based on new 2-adamantane containing poly(aryl ether ketone) for vanadium redox flow battery applications

Zhang, Bengui; Wang, Qi; Guan, Shanshan; Weng, Zhihuan; Zhang, Enlei; Wang, Guosheng; Zhang, Zhigang; Hu, Jingwei; Zhang, Shouhai

doi:10.1016/j.jpowsour.2018.07.050

Cited by 65 publications

(38 citation statements)

References 37 publications

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“…Various polyketones like poly(ether ether ketone) (PEEK), [89] poly(phthalazinone ether ketone) (PPEK), [90] poly(phthalazinone ether ketone ketone) (PPEKK), [91] poly(aryl ether ketone) (PAEK), [92] cardo-poly(ether ketone) (PEK-C), [93] polysulfones like poly(arylene ether sulfone) (PAES), [94] poly(ether sulfone) (PES), [87,95] polysulfone (PSF or PSU), [96] and poly(phenyl sulfone) (PPSU), [96] polyolefins like Diels Alder poly(phenylene) (DAPP), [97] polyethers like poly(fluorenyl ether) (PFE) [98] and poly (ethylene) (PE), [99] Adv. Various polyketones like poly(ether ether ketone) (PEEK), [89] poly(phthalazinone ether ketone) (PPEK), [90] poly(phthalazinone ether ketone ketone) (PPEKK), [91] poly(aryl ether ketone) (PAEK), [92] cardo-poly(ether ketone) (PEK-C), [93] polysulfones like poly(arylene ether sulfone) (PAES), [94] poly(ether sulfone) (PES), [87,95] polysulfone (PSF or PSU), [96] and poly(phenyl sulfone) (PPSU), [96] polyolefins like Diels Alder poly(phenylene) (DAPP), [97] polyethers like poly(fluorenyl ether) (PFE) [98] and poly (ethylene) (PE), [99] Adv.…”

Section: Wwwadvsustainsyscommentioning

confidence: 99%

“…The structures of side chain can vary the morphology of membrane, influencing the vanadium ions permeability and the chemical stability. [92] The adamantane groups induce the improved hydrophobicity and hence narrows the hydrophilic channels, limiting the ions transport. [89] IEC is dependent on the number of ionic groups.…”

Section: Wwwadvsustainsyscommentioning

confidence: 99%

“…To solve the problems, AEMs with various polymer backbones have been studied for VRFBs. Various polyketones like poly(ether ether ketone) (PEEK), poly(phthalazinone ether ketone) (PPEK), poly(phthalazinone ether ketone ketone) (PPEKK), poly(aryl ether ketone) (PAEK), cardo‐poly(ether ketone) (PEK‐C), polysulfones like poly(arylene ether sulfone) (PAES), poly(ether sulfone) (PES), polysulfone (PSF or PSU), and poly(phenyl sulfone) (PPSU), polyolefins like Diels Alder poly(phenylene) (DAPP), polyethers like poly(fluorenyl ether) (PFE) and poly (ethylene) (PE), and poly(benzimidazole) (PBI)95a,100 have been developed as polymer backbones for VRFBs.…”

Section: Anion Exchange Membranesmentioning

confidence: 99%

“…Furthermore, introducing the rigid groups onto the backbone of polymer is a promising method to enhance the mechanical stability. The rigid adamantane groups were incorporated into the backbone of PAEK . The adamantane groups induce the improved hydrophobicity and hence narrows the hydrophilic channels, limiting the ions transport.…”

Section: Anion Exchange Membranesmentioning

confidence: 99%

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The Structure–Activity Relationship in Membranes for Vanadium Redox Flow Batteries

Jiang

Xiang

et al. 2019

Advanced Sustainable Systems

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IntroductionWith the rapid increase of consumption of fossil fuels and the consequent environment pollution, there is an urgent need for the development and effective utilization of renewable energy sources like wind, solar, biomass, etc. However, these renewable energy sources are intermittent in nature, leading to the conflict between the seasonal and unstable electricity generation and requirement of the continuous and stable power supply for the end application. Thereby, energy storage Vanadium redox flow batteries (VRFBs) are regarded as one of the most promising electrochemical technologies for grid-connected renewable energy storage systems. The performance of VRFBs, however, strongly depends on the membrane, one of the key components of VRFBs with critical dual functions of promotion of diffusion of active species (H + , H 3 O + , SO 4 2−, or SO 4 H − ) and inhibition of crossover of vanadium ions. This is intrinsically related to the microstructure of membranes. For example, large and connected ionic clusters or pores in membranes are favorable for the ion transfer, but detrimental to the ion selectivity. While small and isolated hydrophilic ion clusters or pores suppress the water uptake and ion transfer, the decreased swelling ratio would enhance chemical stability of membrane. Thus, comprehensive strategies are required to realize the optimal balance between the ion selectivity, proton conductivity, and chemical stability. This review focuses on the effects of microstructure of membranes on the ion transfer and the chemical stability, including introduction of the rigid groups, electron-withdrawing groups, and hydrophobic backbones, are reviewed. The prospect of the development of membranes with high ion selectivity and high-performance VRFBs is discussed.

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Section: Wwwadvsustainsyscommentioning

confidence: 99%

Section: Wwwadvsustainsyscommentioning

confidence: 99%

Section: Anion Exchange Membranesmentioning

confidence: 99%

Section: Anion Exchange Membranesmentioning

confidence: 99%

See 2 more Smart Citations

The Structure–Activity Relationship in Membranes for Vanadium Redox Flow Batteries

Jiang

Xiang

et al. 2019

Advanced Sustainable Systems

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“…[15][16][17][18] Currently, some aromatic polymers are being actively explored to prepare CEMs and anion exchange membranes (AEMs) for VRBs. 12,[19][20][21][22][23][24][25][26][27][28][29][30][31] Generally, CEMs with anionic groups (most oen sulfonic groups) possess desirable proton conductivity but suffer from serious vanadium ion crossover. On the contrary, AEMs with cationic groups, including quaternary ammonium, imidazolium and pyridinium groups, can effectively constrict vanadium ion contamination and self-discharge due to the Donnan exclusion effect.…”

Section: Introductionmentioning

confidence: 99%

Sulfonated component-incorporated quaternized poly(phthalazinone ether ketone) membranes with improved ion selectivity, stability and water transport resistance in a vanadium redox flow battery

et al. 2019

Self Cite

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Structural Design and Property Study on Flexible Electronic Films with High Heat Resistance and Friction Durability

Wang

Zhang

et al. 2021

Adv Materials Technologies

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To improve both thermal stability and friction durability of flexible electronic films with nano‐Ag, a series of flexible films with dendric nano‐Ag embedded into high thermally stable 2‐adamantane containing poly(aryl ether ketone) (2‐ADMPEK, PAEK) substrates are prepared in this work. These films are named as PAEK‐dnAg. The dendric nanostructure of Ag conductive layer performs excellent conductivity with sheet resistance as low as 0.3959 Ω ◻−1. The wide‐angle X‐ray diffraction and scanning electron microscope (SEM) results show dendric nano‐Ag layer well incorporated to PAEK substrates. The results of thermal stability, hydrolysis–oxidation test, adhesion test, and friction durability indicate the PAEK substrate can effectively protect dendric nanosilver conductive layer from heat, harsh oxidation, and friction. The SEM images further show the dendric embedded structure can remain almost unchanged after high temperature (400 °C) heating in air, water boiling oxidation for 12 h, 2500‐cycle 3M tape peeling test, and harsh friction with sanding paper under 5 N, which should lead to the excellent durability of PAEK‐dnAg samples in harsh condition. Thus, PAEK‐dnAgs may show great potential in flexible electronic films application for harsh condition such as high temperature, hydrothermal environment or high friction.

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High performance membranes based on new 2-adamantane containing poly(aryl ether ketone) for vanadium redox flow battery applications

Cited by 65 publications

References 37 publications

The Structure–Activity Relationship in Membranes for Vanadium Redox Flow Batteries

The Structure–Activity Relationship in Membranes for Vanadium Redox Flow Batteries

Sulfonated component-incorporated quaternized poly(phthalazinone ether ketone) membranes with improved ion selectivity, stability and water transport resistance in a vanadium redox flow battery

Structural Design and Property Study on Flexible Electronic Films with High Heat Resistance and Friction Durability

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