High-performance liquid chromatography method for ferric iron chelators using a post-column reaction with Calcein Blue

Ariga, Tomoko; Ito, Kyoko; Imura, Yoshimi; Yoshimura, Etsuro

doi:10.1016/j.jchromb.2015.01.027

Cited by 4 publications

(3 citation statements)

References 27 publications

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“…A novel detection system for FIC was presented, with which the dequenching of Fe(III)-Calcein Blue (CB; 4-methylumbelliferone-8-methyleneiminodiacetic acid) was exploited. This system has the feature that the signal intensity correlates with the binding strength of the FICs to Fe(III) [29]. Using this methodology, the detection limit of Cit was 72 pmol.…”

Section: Introductionmentioning

confidence: 99%

Determination of ferric iron chelators by high-performance liquid chromatography using luminol chemiluminescence detection

Ariga

Imura

Suzuki

et al. 2016

Journal of Chromatography B

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Section: Introductionmentioning

confidence: 99%

Determination of ferric iron chelators by high-performance liquid chromatography using luminol chemiluminescence detection

Ariga

Imura

Suzuki

et al. 2016

Journal of Chromatography B

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“…Various effective analytical methods, such as atomic absorption spectrometry [6], inductively coupled plasma mass spectrometry [7], liquid chromatography [8], and inductively coupled plasma optical emission spectrometry [9] are successfully applied for 2 of 13 Fe(III) determination. Despite the high sensitivity of these methods, they are complex and time-consuming, and usually require expensive equipment that is operated by skilled personnel.…”

Section: Introductionmentioning

confidence: 99%

Mercaptosuccinic-Acid-Functionalized Gold Nanoparticles for Highly Sensitive Colorimetric Sensing of Fe(III) Ions

et al. 2021

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The development of reliable and highly sensitive methods for heavy metal detection is a critical task for protecting the environment and human health. In this study, a qualitative colorimetric sensor that used mercaptosuccinic-acid-functionalized gold nanoparticles (MSA-AuNPs) to detect trace amounts of Fe(III) ions was developed. MSA-AuNPs were prepared using a one-step reaction, where mercaptosuccinic acid (MSA) was used for both stabilization, which was provided by the presence of two carboxyl groups, and functionalization of the gold nanoparticle (AuNP) surface. The chelating properties of MSA in the presence of Fe(III) ions and the concentration-dependent aggregation of AuNPs showed the effectiveness of MSA-AuNPs as a sensing probe with the use of an absorbance ratio of A530/A650 as an analytical signal in the developed qualitative assay. Furthermore, the obvious Fe(III)-dependent change in the color of the MSA-AuNP solution from red to gray-blue made it possible to visually assess the metal content in a concentration above the detection limit with an assay time of less than 1 min. The detection limit that was achieved (23 ng/mL) using the proposed colorimetric sensor is more than 10 times lower than the maximum allowable concentration for drinking water defined by the World Health Organization (WHO). The MSA-AuNPs were successfully applied for Fe(III) determination in tap, spring, and drinking water, with a recovery range from 89.6 to 126%. Thus, the practicality of the MSA-AuNP-based sensor and its potential for detecting Fe(III) in real water samples were confirmed by the rapidity of testing and its high sensitivity and selectivity in the presence of competing metal ions.

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“…Various analytical methods, such as atomic absorption spectrometry [2], inductively couple plasma mass spectrometry [3], liquid chromatography [4], and spectrophotometric [5] and fluorescent [6] methods, are successfully applied for Fe(III) determination. Despite the high sensitivity of these methods, they are complex and time-consuming, and usually require expensive equipment operated by skilled personnel.…”

Section: Introductionmentioning

confidence: 99%

Gold Nanoparticles Functionalized with Mercaptosuccinic Acid as a Means for Detecting Fe(III) Ions

Komova

Serebrennikova

Berlina

et al. 2021

The 1st International Electronic Conference on Chemical Sensors and Analytical Chemistry

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The application of mercaptosuccinic acid-capped gold nanoparticles as a sensing probe for the colorimetric detection of Fe(III) is reported. The well-dispersed gold nanoparticles (AuNPs) with a diameter of around 20 nm were obtained by a one-step reaction of tetrachloroauratic acid with mercaptosuccinic acid (MSA) as a reducing and capping agent, respectively. Fe(III) reportedly causes the aggregation of prepared MSA-capped AuNPs followed by a change in color and a shift to long wavelengths in the absorbance spectra. The resulting method allows for a visual and spectrophotometric Fe(III) determination with detection limits of 30 ng/mL and 23 ng/mL, respectively. MSA-capped AuNPs have been used as sensing probes for the detection of Fe(III) in drinking water samples with a detection limit that is much lower than the maximum permissible level of Fe(III) specified by official regulations (300 ng/mL).

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High-performance liquid chromatography method for ferric iron chelators using a post-column reaction with Calcein Blue

Cited by 4 publications

References 27 publications

Determination of ferric iron chelators by high-performance liquid chromatography using luminol chemiluminescence detection

Determination of ferric iron chelators by high-performance liquid chromatography using luminol chemiluminescence detection

Mercaptosuccinic-Acid-Functionalized Gold Nanoparticles for Highly Sensitive Colorimetric Sensing of Fe(III) Ions

Gold Nanoparticles Functionalized with Mercaptosuccinic Acid as a Means for Detecting Fe(III) Ions

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