“…In case of TIs, it is also interesting to note that a layered material exhibits rhombohedral structure with in R 3 m (D5) space group. Apart from being a known TI and TE, the Sb 2 Te 3 holds great promise as a phase changing material for information storage in chalcogenide alloys [18].Various synthesis techniques; such as Bridgman crystal growth, chemical vapour deposition (CVD), pulsed-laser deposition (PLD), flux free method, metal organic chemical vapour deposition (MOCVD), and molecular beam epitaxy (MBE) have been employed to grow bulk single crystals, thin films, nano-plates/nano-ribbons and nanosheets of TI and topological superconductor (TSC) materials [6,17,19,[26][27][28][29][30][31][32][33][34][35][36][37]. Interestingly, there are relatively less reports on the synthesis of bulk singly crystalline TI materials, using the flux free method.…”