1969
DOI: 10.1103/physrev.182.244
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High-Order Perturbation Theory for the Bound States of an Electron in a Screened Coulomb Potential

Abstract: The solution to the nonrelativistic Schrodinger equation for a bound electron in an attractive screened Coulomb potential is investigated using the large-Z (Z is nuclear charge) asymptotic expansion theory. Both the basic asymptotic and perturbation solutions are found. The problem of finding the feth order perturbation wave function and energy for any state is reduced to solving, recursively, a set of k linear algebraic equations in k unknowns. The asymptotic expansions for the energy and wave functions are p… Show more

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Cited by 73 publications
(10 citation statements)
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“…where P nl ͑r͒ is the radial wave function for the nlth shell. The numerical solutions 26 and higher order perturbation calculation 27 have been evaluated for Eq. ͑1͒.…”
Section: Theorymentioning
confidence: 99%
“…where P nl ͑r͒ is the radial wave function for the nlth shell. The numerical solutions 26 and higher order perturbation calculation 27 have been evaluated for Eq. ͑1͒.…”
Section: Theorymentioning
confidence: 99%
“…Although the range of r is infinite, this expansion is intuitively reasonable for eigenstates where the extent of the electron cloud is small compared with D ; empirical justification comes from the agreement of the resulting energies with numerical calculations at large D (Iafrate and Mendelsohn 1969).…”
mentioning
confidence: 87%
“…However Iafrate and Mendelsohn (1969) have shown variationally that ( I , + 2 2G/e which, when combined with (6) yields, (2G/e)1'2 -1 ,< I , < (2G/e + &)l" -+.…”
Section: Some Properties Of the Screened Coulomb Potentialmentioning
confidence: 98%