Heteropolyacid/saponite-like clay complexes and their blends in amphiphilic SEBS

Vuillaume, Pascal Y.; Mokrini, Asmae; Siu, Ana; Théberge, Karine; Robitaille, Lucie

doi:10.1016/j.eurpolymj.2009.01.001

Cited by 18 publications

(7 citation statements)

References 51 publications

(56 reference statements)

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“…Many researchers are interested in hydrocarbon polymers with an aliphatic main chain for PEMs. However, this kind of PEM is mainly used for low-temperature PEMFC or DMFC due to the inferior oxidative stability of these aliphatic main-chain hydrocarbon polymers. − The frequently used aliphatic main-chain hydrocarbon polymers include varieties of styrene-based block copolymers, CS, poly(vinyl alcohol) (PVA), and so on. To enhance mechanical strength, methanol barrier, or proton conductivity, these polymers often require doping with inorganic proton-conducting moieties, blending with polymer pairs, or forming into IPNs.…”

Section: Nonfluorinated Acid Ionomer Membranesmentioning

confidence: 99%

Recent Development of Polymer Electrolyte Membranes for Fuel Cells

2012

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Membranes with Proton-Conducting Polymer Components 2793 4. Nonfluorinated Acid Ionomer Membranes 2793 4.1. Poly(arylene ether)-Based Membranes 2793 4.1.1. Modification of SPEEK Membrane 2793 4.1.2. Poly(arylene ether)s with Cross-Linkable Groups 2794 4.1.3. Poly(arylene ether)s with Pendant Sulfonated Groups or Side-Chains 2799 4.1.4. Poly(arylene ether)s with Backbones Containing Heteroatoms Such as F, N, S, and P 2800 4.1.5. Multiblock Copoly(arylene ether)s Synthesized by the Coupling Reaction of Hydrophilic and Hydrophobic Macromonomers 2803 4.2. Polyimide-Based Membranes 2804 4.2.1. SPIs Based on NTDA 2804 4.2.2. SPIs based on BNTDA 2806 4.2.3. SPIs Based on Other Dianhydrides 2807 4.3. Hydrocarbon Polymer with Aliphatic Main-Chain-Based Membranes 2807 4.4. Glass Membranes 2809 5. Polybenzimidazole/H 3 PO 4 Membranes 2809 5.1. Modifications to mPBI 2810 5.1.1. Optimizations of Preparation and Operation of Acid-Doped mPBI System 2810 5.1.2. Modified mPBI/H 3

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Section: Nonfluorinated Acid Ionomer Membranesmentioning

confidence: 99%

Recent Development of Polymer Electrolyte Membranes for Fuel Cells

2012

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“…Vuillaume et al . used phosphotungstic acid modified saponite clay to prepare styrene/ethylene‐co‐butylene/styrene block copolymer based nanocomposites . Hrobarikova et al .…”

Section: Sustainable Rubber Additivesmentioning

confidence: 99%

Sustainable rubbers and rubber additives

Sarkar

Bhowmick

2017

J of Applied Polymer Sci

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Rubber is one of the most versatile materials having myriad of applications-from niche rubber band and eraser to highly engineered spacecraft seal. Of late, the glittering concept of "sustainability" has been able to infiltrate within the domain of elastomer science and technology to a significant extent -in both academia and industry. This fervent context thus necessitates a systematic documentation of brief history, present research scenario and future perspective of sustainable developments in this field. The present review aims to portray a panoramic sketch of various sustainable rubbers and functional rubber additives in this field and intends to provide a direction to their plausible future developments.

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“…HPAs are nanosized metal–oxygen anion clusters with a unique variety in structure and strong acidity . HPA compounds include a metal (such as tungsten, molybdenum, or vanadium), oxygen, acidic hydrogen atoms, and a element generally from the p‐block (such as silicon, phosphorus) .…”

Section: Intermediate Temperature Proton‐conducting Membrane Electrolmentioning

confidence: 99%

“…HPA compounds include a metal (such as tungsten, molybdenum, or vanadium), oxygen, acidic hydrogen atoms, and a element generally from the p‐block (such as silicon, phosphorus) . HPAs have different hydrated structures (Keggin and Dowson Structures), and the Keggin structure (H n XM 12 O 40 ) was a well‐known structure, which consists of a central atom in a tetrahedral arrangement of oxygen atoms surrounded by 12 oxygen octahedra connected with tungsten or molybdenum because its ease of preparation and strong acidity . HPA molecules bridge water moieties through formation of hydronium ions such as H + , H 3 O + , H 5 O 2 + , so HPAs act toward the water of hydration, which is generally loosely bound in the structure for high proton conductivity .…”

Section: Intermediate Temperature Proton‐conducting Membrane Electrolmentioning

confidence: 99%

Intermediate temperature proton‐conducting membrane electrolytes for fuel cells

Scott

2013

WIREs Energy & Environment

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This review provides an overview of intermediate temperature proton-conducting membrane electrolyte materials for fuel cells. Such fuel cells operate in the approximate temperature range of 150-300 • C and can capitalize on a number of technological reasons for operating H 2 /air. These reasons include enhancement of electrochemical kinetics, simplified water management, efficient cooling, and useful waste heat recovery. Importantly lower quality, for example, reformed hydrogen, containing relatively large amounts of carbon dioxide, may be used as the fuel. The materials, which have been the focus of intermediate temperature proton-conducting fuel cells, include heteropolyacids, metal pyrophosphates, solid acids, and acid-imbibed high-temperature polymers such as polybenzimidazole. C 2013 John Wiley & Sons, Ltd.

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Heteropolyacid/saponite-like clay complexes and their blends in amphiphilic SEBS

Cited by 18 publications

References 51 publications

Recent Development of Polymer Electrolyte Membranes for Fuel Cells

Recent Development of Polymer Electrolyte Membranes for Fuel Cells

Sustainable rubbers and rubber additives

Intermediate temperature proton‐conducting membrane electrolytes for fuel cells

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