Heteroleptic Phenanthroline Complexes of Trinuclear Molybdenum Clusters with Luminescent Properties

Abstract

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In Situ Generation of Active Molybdenum Octahedral Clusters for Photocatalytic Hydrogen Production from Water

“…[2] In particular,m olybdenum and tungsten sulfides, including triangular clusters, were reportedt ob ee fficient electrocatalysts for the generation of hydrogen. [3][4][5][6][7][8][9][10][11] Jaramillo et al reported the hydrogen evolution reaction(HER) of the Mo IV [Mo 3 S 4 (H 2 O) 9 ] 4 + clusterc omplex supported on highly oriented pyrolytic graphite (HOPG) under electrochemical conditions, and ah igh turnover frequency (TOF) value (0.07 s À1 )p er cluster molecule wasa chieved. [12] Other molybdenum-sulfur and tungsten-sulfur complexes were studied in the HER under photochemical conditions, for which the presence of ap hotosensitizer and as acrificial donor is needed.…”

What kind of interactions we may get moving from zwitter to “dritter” ions: C–O⋯Re(O4) and Re–O⋯Re(O4) anion⋯anion interactions make structural difference between l-histidinium perrhenate and pertechnetate

“…An analysis of noncovalent interactions in compounds of metals and bioorganic molecules can provide valuable data on the properties of compounds, in terms of recognition processes 5 and receptor-information chains, 6 the influence of co-factors, 7 and also for the interpretation of intermolecular energy transfer processes. 8 Even weak intermolecular interactions affect the properties such as luminescence, 9,10 solubility in different solvents, 11 phase transition temperature 12 and type.…”