2023
DOI: 10.1007/s42864-023-00210-8
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Hetero-bimetallic transition metal-substituted Krebs-type polyoxometalate with N-chelating ligand as anticancer agents

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Cited by 11 publications
(5 citation statements)
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“…With the development of science and technology and functional materials, there have been increasing numbers of interdisciplinary articles reported in recent decades. The applications of POMs not only are any longer focused on catalytic, magnetic, and luminescence but also have been extended toward the explorations of enzyme-like activity, electrochemical sensing, etc. Although POMs with remarkable redox activity have been proven to be potential electrode materials, their application in electrochemical sensors is greatly restricted owing to the shortcomings of poor conductivity. Therefore, some multifunctional composite materials, which combined POMs with metal nanoparticles (NPs), metal–organic frameworks, covalent–organic frameworks, carbonaceous materials, and conducting polymers, were fabricated to take advantage of synergistic effects to improve conductive properties. The results indicate that the electrochemical sensors of carbon–POM nanomaterials can exhibit a low detection limit, high selectivity, and good antijamming capability.…”
Section: Resultsmentioning
confidence: 99%
“…With the development of science and technology and functional materials, there have been increasing numbers of interdisciplinary articles reported in recent decades. The applications of POMs not only are any longer focused on catalytic, magnetic, and luminescence but also have been extended toward the explorations of enzyme-like activity, electrochemical sensing, etc. Although POMs with remarkable redox activity have been proven to be potential electrode materials, their application in electrochemical sensors is greatly restricted owing to the shortcomings of poor conductivity. Therefore, some multifunctional composite materials, which combined POMs with metal nanoparticles (NPs), metal–organic frameworks, covalent–organic frameworks, carbonaceous materials, and conducting polymers, were fabricated to take advantage of synergistic effects to improve conductive properties. The results indicate that the electrochemical sensors of carbon–POM nanomaterials can exhibit a low detection limit, high selectivity, and good antijamming capability.…”
Section: Resultsmentioning
confidence: 99%
“…POM-based inorganic–organic hybrids have better cell penetration, increased selectivity, and decreased toxicity because of changes in their surface structure, charge, and polarity. 61 …”
Section: Resultsmentioning
confidence: 99%
“…These characteristics make them highly promising for a range of applications in various catalytic reactions [36][37] and electrocatalysis, [38][39] and other electrochemical reactions. [40][41][42][43][44][45][46][47][48][49][50][51][52][53][54][55][56][57][58] In 2018, Dong, Cronin, and their co-workers developed a dual-function Lewis acid and base catalyst for LiÀ S batteries in the form of an Ag(I)-substituted Keggin K 3 [H 3 AgIPW 11 O 39 ] cluster. LiPSs can be strongly adsorbed on the {AgIPW 11 O 39 } cluster.…”
Section: Introductionmentioning
confidence: 99%
“…These compounds exhibit an impressive open nanocluster structure, multi‐electron redox properties, and stability in their cluster structure throughout reduction‐oxidation processes. These characteristics make them highly promising for a range of applications in various catalytic reactions [36–37] and electrocatalysis, [38–39] and other electrochemical reactions [40–58] . In 2018, Dong, Cronin, and their co‐workers developed a dual‐function Lewis acid and base catalyst for Li−S batteries in the form of an Ag(I)‐substituted Keggin K 3 [H 3 AgIPW 11 O 39 ] cluster.…”
Section: Introductionmentioning
confidence: 99%