“…Subsequently, Tajima et al prepared peroxoiron(III) complexes by the reaction of H2O2 with the corresponding porphyrin complex (TPP or OEP) and by the reduction of the dioxygen adduct of an iron(II) porphyrin complex and confirmed the accompanying ESR spectral features. [168][169][170][171] The occurrence of two species having the characteristic small anisotropic splitting was explained by assuming different levels of protonation of the bound peroxide.…”
“…Subsequently, Tajima et al prepared peroxoiron(III) complexes by the reaction of H2O2 with the corresponding porphyrin complex (TPP or OEP) and by the reduction of the dioxygen adduct of an iron(II) porphyrin complex and confirmed the accompanying ESR spectral features. [168][169][170][171] The occurrence of two species having the characteristic small anisotropic splitting was explained by assuming different levels of protonation of the bound peroxide.…”
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