The syntheses and characterizations of the first bismuthanylborane monomers stabilized only by a donor in D·BH2Bi(SiMe3)2 (D = DMAP 1a, IDipp 1b, IMe4 1c; DMAP = 4-dimethylaminopyridine, IDipp = 1,3-bis(2,6-diisopropylphenyl)-imidazolin-2-ylidene,...