Three-dimensional direct numerical simulations with detailed chemistry were conducted to investigate the effect of equivalence ratio on spatial variations of the heat release rate and flame markers of hydrogen/carbon monoxide syngas expanding spherical premixed flames under turbulent conditions at elevated pressures. The flame structures and the heat release rate were analysed in detail for fuel-lean, stoichiometric and fuel-rich centrally ignited spherical flames. The equivalence ratio changes the balance among thermodiffuive effects, Darrieus-Landau instability and turbulence, leading to different flame dynamics and the heat release rate distribution, despite exhibiting similar cellular and wrinkling flames. The Darrieus-Landau instability is relatively insensitive to the equivalence ratio while the thermo-diffuive process is strongly affected by the equivalence ratio. As the thermo-diffusive effect increases as the equivalence ratio increases, the fuel-lean flame is more unstable than the fuel-rich flame with the stoichiometric flame in between, under the joint effects of the Darrieus-Landau instability and the thermo-diffusive effect. The local heat release rate and curvature display a positive correlation for the lean flame, no correlation for the stoichiometric flame, and negative correlation for the rich flame. Furthermore, the low and high heat release rate values for the fuel-lean flame are found in the negative and positive curvature zones, respectively, while the oppostite trends are found in fuel-rich flame. It is found that heat release rate markers based on species concentrations vary strongly with changing equivalence ratio. The results suggest that the HCO concentration and product of OH and CH2O concentrations show good correlation with the local heat release rate for H2/CO syngas-air stoichiometric flame under turbulent conditions at elevated pressures.3