2019
DOI: 10.1002/ejic.201900258
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Halogen‐ and Counterion‐Modulated Photochromic and Photoluminescence Properties of Haloargentate Hybrids

Abstract: Five haloargentate hybrids with isostructural 1D [Ag 2 X 3 ] n n-(X = Br/I) anionic chains have been designed and solvothermally synthesized with saturated tetraethylammonium (TEA + ) and unsaturated methylated/ethylated 3-cyanopyridinium (MCP + /ECP + ) cations, which show reversible photochromic [a]

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Cited by 15 publications
(6 citation statements)
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“…3− polymeric chain. [53][54] Insets in (g) and (h) show the corresponding plots of the PL intensity vs excitation power. (i) A CIE 1931 plot with the emission colors of (TEP)2Cu2Br4 and (TEP)2Cu4Br6.…”
Section: Synthesis and Structurementioning
confidence: 99%
“…3− polymeric chain. [53][54] Insets in (g) and (h) show the corresponding plots of the PL intensity vs excitation power. (i) A CIE 1931 plot with the emission colors of (TEP)2Cu2Br4 and (TEP)2Cu4Br6.…”
Section: Synthesis and Structurementioning
confidence: 99%
“…As an important member of the metal halide family, organic–inorganic haloargentate hybrids have always fascinated researchers, and this is due to not only their structural diversity, ranging from discrete blocks to three-dimensional (3D) systems, but also their multiple applicable natures in nonlinear optical properties, visible light catalysis, photochromism, piezochromism, and switchable dielectrics . On the other hand, the thermally stimulated phase transition materials often bring about interesting physical properties such as fluorescence, thermochromism, , ferroelectricity, and so on.…”
Section: Introductionmentioning
confidence: 99%
“…Common inorganic photochromic factors include silver halides, 24,25 transition metal oxides (e.g. TiO 2 , WO 3 ), [26][27][28][29][30][31][32] and polyoxometalates (POMs).…”
Section: Introductionmentioning
confidence: 99%