2011
DOI: 10.1002/pssa.201026545
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Growth temperature altered morphology of Ge nanocolumns

Abstract: Germanium nanocolumns grown by glancing angle deposition on Si(100) substrates and prepatterned substrates comprising of SiO2 nanospheres demonstrated an altered morphology that is greatly influenced by the substrate temperature (TS). Surface diffusion‐driven mass transport and increased adatom mobility at homologous temperatures TS/TM ≈ 0.34 and 0.39 (TM melting temperature of Ge) augmented fibrous‐columnar and intracolumnar growth, respectively. Further increment of the substrate temperature provoked column … Show more

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Cited by 13 publications
(8 citation statements)
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References 35 publications
(52 reference statements)
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“…Fih, GLAD is adaptable to a wide variety of materials, including low T m (T m : melting point) materials (e.g. Ag, 2 Au, 3 Cu, 4 Al, 5 Ge, 6 tris(8-hydroxyquinolinato) aluminium, 7 C 60 , 8 zinc phthalocyanine 9 ) and high T m species (e.g. Si, 10 SiO 2 , 11 TiO 2 , 12 Al 2 O 3 , 13 ZrO 2 , 14 HfO 2 , 15 MgF 2 , 16 indium tin oxide (ITO), 17 InN, 18 WO 3 , 19 Ta, 20 W, 21 Fe, 22 Cr, 23 Co 24 ).…”
Section: Introductionmentioning
confidence: 99%
“…Fih, GLAD is adaptable to a wide variety of materials, including low T m (T m : melting point) materials (e.g. Ag, 2 Au, 3 Cu, 4 Al, 5 Ge, 6 tris(8-hydroxyquinolinato) aluminium, 7 C 60 , 8 zinc phthalocyanine 9 ) and high T m species (e.g. Si, 10 SiO 2 , 11 TiO 2 , 12 Al 2 O 3 , 13 ZrO 2 , 14 HfO 2 , 15 MgF 2 , 16 indium tin oxide (ITO), 17 InN, 18 WO 3 , 19 Ta, 20 W, 21 Fe, 22 Cr, 23 Co 24 ).…”
Section: Introductionmentioning
confidence: 99%
“…While the cluster ions travel in a horizontal plane, the effusion cell and the triple evaporator are attached to the deposition chamber pointing almost vertically upward: They are rotated by 70 • from the horizontal and laterally by ±17 • to different sides with the rotation center equal to the sample position, as shown in the sketch of the CIBD system in Figure 1. In order to avoid columnar growth of the matrix due to shadowing effects [43], Fe-Ge samples were tilted by 35 • from the horizontal for deposition. A side effect of the differing deposition angles is an offset between cluster ion beam, effusion cell and triple evaporator deposition areas due to the used deposition mask.…”
Section: Methodsmentioning
confidence: 99%
“…The mass flow of f O2 ¼ 160 sccm was kept constant for t O2 ¼ 10 and 14 min (for D ¼ 535 nm) and t O2 ¼ 14 and 35 min (for D ¼ 722 nm) to achieve isolated PS nanospheres of diameters D plasma ¼ 200 and 100 nm, respectively, as schematically sketched in Fig. After the patterning procedure, ion beam sputter GLAD of Ge was carried out in a high vacuum deposition chamber with a base pressure 1.0 Â 10 À8 mbar as described elsewhere [8][9][10]21,[26][27][28] . Subsequently, in order to produce cylindrical Si seeds on these substrates, inductively coupled plasma reactive ion etching was performed 24,25 (ICP-RIE: Plasmalab 100 Oxford Instruments Plasma Technology) with an ICP source (2 MHz, 1200 W) and an RIE source (13.56 MHz, 45 W).…”
Section: Methodsmentioning
confidence: 99%
“…[7][8][9][10] Such sculptured thin films offer multiple applications, namely in photonic crystals, 11 polarization filters, 12 antireflection coatings, 13 biosensing, 14,15 pressure sensing, 16 and humidity sensing. 21 Instead, it may be possible to grow Ge nanostructures on Si patterned substrates at room temperature, and then alternatively retain the distinct GLAD morphologies upon post-deposition annealing processes. Even though the required crystalline Ge-GLAD nanostructures can, in principle, be obtained by depositing films at elevated substrate temperatures, the GLAD-inherent columnar morphology is significantly altered by diffusion-driven processes.…”
Section: Introductionmentioning
confidence: 99%