International audienceWe propose to grow III-V quantum nanostructures by molecular beam epitaxy on GaP substrates and GaP layers almost lattice-matched to Si. These nanostructures will be used as active zone in light emitters on silicon. We first present photoluminescence results for GaAsP/GaP QWs. A comparison with electronic band lineups is performed. The GaP/Si interface is studied by Raman spectroscopy