Growth of CsLiB6O10 crystals with high laser-damage tolerance

Nishioka, Masato; Kanoh, A.; Yoshimura, Masashi; Mori, Yojiro; Sasaki, T.

doi:10.1016/j.jcrysgro.2004.11.418

Cited by 31 publications

(29 citation statements)

References 6 publications

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“…They are quite well known for their nonlinear optical properties and transparency in the UV range of the electromagnetic spectrum. Most widely used non-linear optical borates are the low temperature modification of barium borate β-BaB 2 O 4 [1][2][3][4], lithium triborate LiB 3 O 5 [5][6][7][8] and lithium-cesium borate CsLiB 6 O 10 [9][10][11]. Fluoride borates stand out amongst other borates, as they possess much broader area of transparency with the cutoff edge shifted further in the UV-range [12,13,16].…”

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confidence: 99%

Fluoride Borates with [(BO₃)F]^4– ↔ [F₄]^4– Anionic Isomorphism and X-ray Sensitivity

Bekker

Solntsev

Yelisseyev

et al. 2016

Crystal Growth & Design

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Crystals of Ba 7 (BO 3 ) 4-y F 2+3y and Ba 4-x Sr 3+x (BO 3 ) 4-y F 2+3y solid solutions display a phenomenon that has never been described for borates before -X-ray irradiation induces strong absorption in the visible range and, as the result, coloring of the crystals up to dark purple. The induced absorption can be removed by illumination with a wavelength of 300−400 nm. Owing to this phenomenon these crystals are promising sensor applicable to fixing X-ray images. With the use of electron spin resonance and optical spectroscopy it has been found that the formation of color centers is connected with the [(BO 3 )F] 4-and [F 4 ] 4-tetrahedral groups, which are the distinguishing feature of Ba 7 (BO 3 ) 4-y F 2+3y and Ba 4-x Sr 3+x (BO 3 ) 4-y F 2+3y structure. Partial replacement of Ba 2+ to Sr 2+ in the crystal lattice of Ba 4-x Sr 3+x (BO 3 ) 4-y F 2+3y leads to the formation of the stable electron-hole pairs under X-ray irradiation. The opportunity to vary the cationic and anionic sublattice composition within the same crystal structure becomes a prospective tool to vary physical and chemical properties of the phosphors.

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confidence: 99%

Fluoride Borates with [(BO₃)F]^4– ↔ [F₄]^4– Anionic Isomorphism and X-ray Sensitivity

Bekker

Solntsev

Yelisseyev

et al. 2016

Crystal Growth & Design

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“…Various borate-based single crystals, including LiB 3 O 5 (Wang et al 1995), CsLiB 6 O 10 (Nishioka et al 2005), La 2 CaB 10 O 19 (Jing et al 2006) have been investigated and reported to be promising from their physical properties view point. These compounds are very attractive particularly for their applications in non-linear photonics.…”

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confidence: 99%

Influence of seeding on crystallization behaviour of BaNaB9O15 glasses

Vaish

Varma

2009

Bull Mater Sci

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Transparent BaNaB 9 O 15 (BNBO) glasses were fabricated via the conventional melt-quenching technique. X-ray powder diffraction (XRD) followed by differential scanning calorimetric (DSC) studies confirmed the amorphous and glassy nature of the as-quenched samples, respectively. The effect of seeding on the crystallization of BNBO glasses was studied by non-isothermal DSC method and was modeled using the JohnsonMehl-Avrami and Ozawa equations. The activation energy for seeded glasses decreased with the increase in fraction of crystallization. The values for the onset of crystallization and Avrami exponent were found to be lower for seeded samples which were associated with the heterogeneous nucleation and epitaxial processes.

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“…We have conventionally grown CLBO crystals from B 2 O 3 Àpoor (B-poor) self-flux solution (Cs 2 CO 3 : Li 2 CO 3 : B 2 O 3 ¼ 1 : 1 : 5:5) as a starting material by the solution-stirring top-seeded solution growth (SS-TSSG) method in an ambient atmosphere and have estimated their UV optical properties [2][3][4]. As a result, we found that the presence of water as an impurity influences UV optical properties such as the bulk laser-induced damage threshold (LIDT) and transmittance [5].…”

Section: Introductionmentioning

confidence: 99%

Crystal growth of in a dry atmosphere and from a stoichiometric melt composition

Kawamura

Yoshimura

Shimizu

et al. 2010

Journal of Crystal Growth

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Growth of CsLiB6O10 crystals with high laser-damage tolerance

Cited by 31 publications

References 6 publications

Fluoride Borates with [(BO₃)F]^4– ↔ [F₄]^4– Anionic Isomorphism and X-ray Sensitivity

Fluoride Borates with [(BO₃)F]^4– ↔ [F₄]^4– Anionic Isomorphism and X-ray Sensitivity

Influence of seeding on crystallization behaviour of BaNaB9O15 glasses

Crystal growth of in a dry atmosphere and from a stoichiometric melt composition

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Growth of CsLiB6O10 crystals with high laser-damage tolerance

Cited by 31 publications

References 6 publications

Fluoride Borates with [(BO3)F]4– ↔ [F4]4– Anionic Isomorphism and X-ray Sensitivity

Fluoride Borates with [(BO3)F]4– ↔ [F4]4– Anionic Isomorphism and X-ray Sensitivity

Influence of seeding on crystallization behaviour of BaNaB9O15 glasses

Crystal growth of in a dry atmosphere and from a stoichiometric melt composition

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Product

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Fluoride Borates with [(BO₃)F]^4– ↔ [F₄]^4– Anionic Isomorphism and X-ray Sensitivity

Fluoride Borates with [(BO₃)F]^4– ↔ [F₄]^4– Anionic Isomorphism and X-ray Sensitivity