Growing layered double hydroxides on CNTs and their catalytic performance for higher alcohol synthesis from syngas

Cao, Ang; Liu, Guilong; Wang, Lianfang; Liu, Jingge; Yue, Yizhi; Zhang, Lihong; Liu, Yuan

doi:10.1007/s10853-016-9823-9

Cited by 55 publications

(41 citation statements)

References 47 publications

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“…The rhodium catalyst developed by Hu et al [20] almost selectively produces ethanol. In other cases high branching probabilities occurred, e.g., for the copper-cobalt catalyst presented in [12] where more than 35 % of the C 3 -C 4 -alcohols are branched. The higher alcohol mixture produced from the modified methanol synthesis catalyst in Ref.…”

Section: Literature Reviewmentioning

confidence: 99%

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Iron‐Based Fischer‐Tropsch Catalysts for Higher Alcohol Synthesis

Schaller

Reichelt

Jahn

2018

Chemie Ingenieur Technik

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A short overview over state‐of‐the‐art synthesis routes to higher alcohols from syngas is given. The literature shows that iron‐based catalysts offer the potential for higher alcohol production but cannot fully compete with catalyst systems based on molybdenum and cobalt so far. However, the results presented in this short communication show that by proper choice of reaction conditions and promotion of the catalysts a promising selectivity to higher alcohols and other oxygenates can also be reached for low‐priced iron‐based catalysts.

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Section: Literature Reviewmentioning

confidence: 99%

“…For the production of linear alcohols, modified Fischer‐Tropsch catalysts can be applied. Cobalt‐based systems are wider investigated, but also iron catalysts , were applied for that purpose. Few publications also dealt with rhodium catalysts , .…”

Section: Literature Reviewmentioning

confidence: 99%

Iron‐Based Fischer‐Tropsch Catalysts for Higher Alcohol Synthesis

Schaller

Reichelt

Jahn

2018

Chemie Ingenieur Technik

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“…Liu and coworkers were able to grow CuCoAl LDHs on carbon nanotubes (CNTs) and on carbon fibers (CFs) . Upon reduction, they obtained Cu‐Co alloy nanoparticles on the surface of the carbon support.…”

Section: Cu‐co‐based Catalystsmentioning

confidence: 99%

Recent Developments in the Conversion of Synthesis Gas to Short‐Chain Alcohols over Cu‐Co‐Based Catalysts

Schmidt

Göbel

Nebel

et al. 2018

Chemie Ingenieur Technik

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Cu‐Co‐based catalysts provide promising systems for higher alcohol synthesis (HAS) due to a synergistic dual‐site mechanism. Bimetallic Cu‐Co (alloy) nanoparticles are assumed to be the active sites, but cobalt carbide (Co2C) forming under reaction conditions also seems to influence the formation of C2+OH. Na‐doped Co‐modified Cu/ZnO/Al2O3 is applied as benchmark catalyst within the Carbon2Chem® subproject L4 providing suitable performance in terms of CO conversion and C2+OH selectivity. However, further optimization is required in order to develop an economically viable HAS process.

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“…Figure (a) is the XRD pattern of CuCo‐pre sample, which can be determined as the double hydroxides . The XRD pattern of the CuCo 2 S 4 is shown in Figure (b).…”

Section: Resultsmentioning

confidence: 63%

Self‐Supporting CuCo₂S₄ Microspheres for High‐Performance Flexible Asymmetric Solid‐State Supercapacitors

et al. 2018

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Copper cobalt sulfide (CuCo 2 S 4 ) microspheres were grown directly on a carbon cloth (CC) substrate via a facile hydrothermal synthesis route. The possible formation mechanism of flower-like CuCo 2 S 4 microspheres was also discussed. The resultant composite was explored as a binder-free electrode for supercapacitors, delivering a high capacitance of 166.67 mAh g -1 at 1 A g -1 , excellent rate capability (108.33 mAh g -1 at 10 A g -1 ) and pronounced long-term cyclability up to 3000 cycles. A flexible solid state supercapacitor was also assembled with binderfree electrode materials and exhibits an energy density of [a]

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Growing layered double hydroxides on CNTs and their catalytic performance for higher alcohol synthesis from syngas

Cited by 55 publications

References 47 publications

Iron‐Based Fischer‐Tropsch Catalysts for Higher Alcohol Synthesis

Iron‐Based Fischer‐Tropsch Catalysts for Higher Alcohol Synthesis

Recent Developments in the Conversion of Synthesis Gas to Short‐Chain Alcohols over Cu‐Co‐Based Catalysts

Self‐Supporting CuCo₂S₄ Microspheres for High‐Performance Flexible Asymmetric Solid‐State Supercapacitors

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Growing layered double hydroxides on CNTs and their catalytic performance for higher alcohol synthesis from syngas

Cited by 55 publications

References 47 publications

Iron‐Based Fischer‐Tropsch Catalysts for Higher Alcohol Synthesis

Iron‐Based Fischer‐Tropsch Catalysts for Higher Alcohol Synthesis

Recent Developments in the Conversion of Synthesis Gas to Short‐Chain Alcohols over Cu‐Co‐Based Catalysts

Self‐Supporting CuCo2S4 Microspheres for High‐Performance Flexible Asymmetric Solid‐State Supercapacitors

Contact Info

Product

Resources

About

Self‐Supporting CuCo₂S₄ Microspheres for High‐Performance Flexible Asymmetric Solid‐State Supercapacitors