“…Peaks of the phosphate group were comparable with peaks at 1,020, 600, and 560 cm -1 , introduced by Kojima and his group in 2018. 16 The presence of the above functional group, hydroxyl group, and phosphate group, show the formation of CPNPs in the HAP phase according to Kojima S. 17 The observed peak at 1,521.83 cm -1 corresponding to the carbonate group is due to the absorption of CO 2 from the atmosphere. 18 On the contrary, the peaks at 1,645.49, 1,725.22, and 3,383.75 cm -1 are attributed to water molecules due to the water adsorption during the synthesis process.…”