“…The T 10 , T 50 and T max are dramatically increased by 32.9, 46.3 and 40.3 C, respectively for PS/CNAPP composites. However, the residues are decreased gradually upon the addition of CNAPP, which can be ascribed to the thermaloxidation degradation of the skeleton of g-C 3 N 4 [41]. These results indicate that the combination of APP and g-C 3 N 4 serves to prevent or slow depolymerization.…”
Section: Thermal Stability Of Ps Compositesmentioning
“…The T 10 , T 50 and T max are dramatically increased by 32.9, 46.3 and 40.3 C, respectively for PS/CNAPP composites. However, the residues are decreased gradually upon the addition of CNAPP, which can be ascribed to the thermaloxidation degradation of the skeleton of g-C 3 N 4 [41]. These results indicate that the combination of APP and g-C 3 N 4 serves to prevent or slow depolymerization.…”
Section: Thermal Stability Of Ps Compositesmentioning
“…S2. Two pronounced peaks were observed at 27.47 and 13.13° in p-CN diffraction pattern corresponding to the interlayer stacking peak of aromatic systems and the in-plane structural packing motif of tri-s-triazine units [36], respectively, which is in consistence with the reported p-CN derived from thermal decomposition of urea [8,33,34]. It is important to note that very similar diffraction patterns with practically identical peak positions were obtained via thermal treatment (temperature range of 520-550 ºC) of melamine [23,25,26,56] and dicyandiamide [11,13,16,18] as source materials.…”
Section: Structural Properties Of P-cnmentioning
confidence: 96%
“…The absorption bands in the region of 1200-1800 cm -1 originate from typical skeletal stretching vibrations of n(C-N) heterocycles (stretching vibrations of triazine ring system)[38,67]. The broad band at 3299 cm -1 was attributed to stretching vibration mode of -NH of hydrogen bonding interaction in partly coordinated groups[36,67]. The band at 2179 cm -1 could be assigned to the stretching vibration of cyano group[29].…”
mentioning
confidence: 94%
“…The p-CN only consists of abundant elements in a tri-s-triazine ring structure as elementary building block. It can be synthesized via a straightforward and scalable process from relatively cheap source materials such as dicyandiamide [10][11][12][13][14][15][16][17][18], cyanamide [19], ammonium thiocyanate [20], melamine [21][22][23][24][25][26][27][28][29][30], urea [8,9,[31][32][33][34][35][36], thiourea [28], guanidine carbonate [37] and thiosemicarbazide [38]. Generally, synthesis methods of p-CN involve thermal treatment of precursor material in the temperature range of 450-650 °C.…”
“…201 However, there is limited research on the composition between LDH and g-C3N4. 166,[201][202][203][204] There is even fewer research on the composition between LDH and g-C3N4 which is used in water purification.…”
Section: Composite and Hybrid Between Carbon Nitride And Ldhmentioning
Dye-polluted water discharged from textile, dyeing, carpet manufacturing, pulp, and paper industries must be properly treated before it is discharged to the environment because the dyes are hazardous to human beings, also can cause problems to the ecosystem.Adsorption and photocatalytic degradation of dyes are promising methods for the treatment of dye-polluted wastewater. Zinc (Zn) aluminium (Al) layered double hydroxide (ZnAl-LDH) materials, and layered double oxides (LDOs) that have semiconductor properties and anionic exchange properties can be used for the removal of anionic dyes. Correspondingly, graphitic carbon nitride (g-C3N4) is a fascinating metal-free semiconductor with synergistic adsorption property due to its polymeric π-conjugated structure, which is a promising photocatalyst in environmental remediation. Therefore, this thesis focuses on developing novel photocatalysts, which is activated under UV (ultraviolet) and/or visible light irradiation with adsorption property for dyes removal from wastewater. The studies include exploring the optimal experimental conditions for the synthesis of LDOs with the best performance in adsorption and photocatalytic degradation, modifying g-C3N4 with carbon black for tuning its adsorption selectivity and improving the photocatalytic activity, and constructing novel inorganic-organic heterogeneous semiconductor composites (ZnAl-LDH@C3N4) with desired adsorption and photodegradation performance toward both cationic and anionic dyes. The relationship between structures, physicochemical properties of photocatalysts and dye removal performances has also been well studied in the thesis.The first part of the experimental chapters focuses on the zinc aluminium layered double hydroxide based photocatalysts. ZnAl-layered double oxide composites (LDOs) were developed to remove anionic dye Orange II sodium salt (OrgII). Synthetic parameters including the molar ratio of Zn to Al, and calcination temperature were adjusted to study the optimal synthetic condition. The relationship between the structural features and the adsorption properties and photocatalytic activity of LDOs was thoroughly investigated.The second part of the experimental chapter focuses on the modification of g-C3N4. Series of carbon black (CB) modified g-C3N4 samples with efficient adsorption and photocatalytic activity were prepared by heating the mixtures of CB and urea. The adsorption and photocatalytic activities were evaluated by removing both cationic dye methylene blue (MB) and anionic dye OrgII. CB modified g-C3N4 exhibited higher photocatalytic activities than pristine g-C3N4. CB worked as both dopant and reactional site during the polycondensation III of urea, which was supposed to increase the crystallisation and condensation degree of g-C3N4. The existing of CB in the g-C3N4 matrix not only enhanced the light absorption for g-C3N4 but also quenched the recombination of charge carriers. Therefore, modified g-C3N4 samples exhibited improved performance for dyes' removal.The third part o...
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